C₆H₄CH₂S₃OCH₂Pt(P(C₆H₅)3)2

Base Information

• Chemical Name: C₆H₄CH₂S₃OCH₂Pt(P(C₆H₅)3)2
• CAS No.: 208833-74-3
• Molecular Formula: C₄₄H₃₈OP₂PtS₃
• Molecular Weight: 936.011
• Mol file: 208833-74-3.mol

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Chemical Property of C₆H₄CH₂S₃OCH₂Pt(P(C₆H₅)3)2

Chemical Property:

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Technology Process of C₆H₄CH₂S₃OCH₂Pt(P(C₆H₅)3)2

There total 1 articles about C₆H₄CH₂S₃OCH₂Pt(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

1,5-dihydro-2,3,4-benzotrithiepin-2-oxide (3886-46-2) + ethylenebis(triphenylphosphine)platinum(0) (12120-15-9) → C6H4CH2S3OCH2Pt(P(C6H5)3)2 (208833-74-3)

Guidance literature:

In toluene; N2-atmosphere; slow addn. of ligand to equimolar amt. of Pt-complex soln. at -60°C, stirring (room temp., 10 h, pptn.); centrifugation, washing (ether), drying (vac.); elem. anal.;

DOI:10.1016/s0020-1693(97)05918-5

Reference yield: 92.0%

C6H4CH2S3OCH2Pt(P(C6H5)3)2 (208833-74-3) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → ((C6H5)2PCH2CH2P(C6H5)2)Pt(S(O)CH2(C6H4)CH2S)

Guidance literature:

In dichloromethane; byproducts: Ph3P=S; N2-atmosphere; stirring Pt-complex soln. with 2 equiv. of phosphine (room temp., 2 h); solvent removal, washing (ether), drying (vac.); elem. anal.;

DOI:10.1016/s0020-1693(97)05918-5

upstream raw materials:

1,5-dihydro-2,3,4-benzotrithiepin-2-oxide

ethylenebis(triphenylphosphine)platinum⁽⁰⁾