Methyl 3-O,4-O-isopropylidene-2-oxo-2-deoxy-beta-D-ribopyranoside

Base Information

Chemical Name:Methyl 3-O,4-O-isopropylidene-2-oxo-2-deoxy-beta-D-ribopyranoside
CAS No.:4096-64-4
Molecular Formula:C₉H₁₄O₅
Molecular Weight:202.207
Hs Code.:
DSSTox Substance ID:DTXSID701158306
Nikkaji Number:J409.283J

Synonyms:SCHEMBL7151062;DTXSID701158306;Methyl 3-O,4-O-isopropylidene-2-oxo-2-deoxy-beta-D-ribopyranoside;Methyl 3,4-O-(1-methylethylidene)-beta-D-erythro-pentopyranosid-2-ulose;4096-64-4

Suppliers and Price of Methyl 3-O,4-O-isopropylidene-2-oxo-2-deoxy-beta-D-ribopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of Methyl 3-O,4-O-isopropylidene-2-oxo-2-deoxy-beta-D-ribopyranoside

Chemical Property:

XLogP3:0
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:1
Exact Mass:202.08412354
Heavy Atom Count:14
Complexity:250

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1(OC2COC(C(=O)C2O1)OC)C
Isomeric SMILES:CC1(O[C@@H]2CO[C@H](C(=O)[C@@H]2O1)OC)C

Technology Process of Methyl 3-O,4-O-isopropylidene-2-oxo-2-deoxy-beta-D-ribopyranoside

There total 2 articles about Methyl 3-O,4-O-isopropylidene-2-oxo-2-deoxy-beta-D-ribopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4096-62-2,4096-64-4,38088-61-8
Methyl-3,4-O-isopropyliden-2-oxo-β-L-erythro-pentosid

Guidance literature:: Gemisch von Methyl-2,4-O-isopropyliden-2-desoxy-2-C-vinyl-β-L-arabinosid u. Methyl-3,4-O-isopropyliden-2-desoxy-2-C-aethyliden-β-arabinosid, Ozonisierung in E. (1.5h) u. anschl. Hydrogenierung (PtO2/Raumtemp., Druck);
DOI:10.1039/jr9650003433

Reference yield:

: 4096-62-2,4096-64-4,38088-61-8
Methyl-3,4-O-isopropyliden-β-D-erythro-pentopyranosidulose

Guidance literature:: Methyl-3,4-isopropyliden-α-L-arabinosid, RuO4/Oxid. (--> Gemisch von Pentopyranosid-2-ulose und dem Gem.-diol);

Reference yield:

: 4096-64-4
methyl 3,4-O-isopropylidene-β-D-erythro-pentopyranosid-2-ulose

: <3R,4R,4aR,10bS>-2,3,4,4a,6,10b-hexahydro-4a-benzyloxy-3,4-dihydroxy-3,4-O-isopropylidenepyrano<3,2-c><2>benzopyran

Guidance literature:: Multi-step reaction with 2 steps

1: 72 percent / diethylamine sulfur trifluoride / CH₂Cl₂

2: Cp₂HfCl₂, AgClO₄ / CH₂Cl₂ / -50 deg C to r.t.

With bis(cyclopentadienyl)hafnium dichloride; diethylamino-sulfur trifluoride; silver perchlorate; In dichloromethane;
DOI:10.1016/S0040-4039(00)77614-3