S-[(2E,6E,10E)-3,7,11,15-Tetramethyl-2,6,10,14-hexadecatetrenyl]-L-cysteine methyl ester

Base Information

Chemical Name:S-[(2E,6E,10E)-3,7,11,15-Tetramethyl-2,6,10,14-hexadecatetrenyl]-L-cysteine methyl ester
CAS No.:136238-12-5
Molecular Formula:C24H41NO2S
Molecular Weight:407.661
Hs Code.:
DSSTox Substance ID:DTXSID701119786
Nikkaji Number:J1.672.402E
Mol file:136238-12-5.mol

Synonyms:SCHEMBL8977914;SCHEMBL8977916;DTXSID701119786;136238-12-5;S-[(2E,6E,10E)-3,7,11,15-Tetramethyl-2,6,10,14-hexadecatetraen-1-yl]-L-cysteine methyl ester;S-[(2E,6E,10E)-3,7,11,15-Tetramethyl-2,6,10,14-hexadecatetrenyl]-L-cysteine methyl ester

Suppliers and Price of S-[(2E,6E,10E)-3,7,11,15-Tetramethyl-2,6,10,14-hexadecatetrenyl]-L-cysteine methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of S-[(2E,6E,10E)-3,7,11,15-Tetramethyl-2,6,10,14-hexadecatetrenyl]-L-cysteine methyl ester

Chemical Property:

XLogP3:7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:15
Exact Mass:407.28580072
Heavy Atom Count:28
Complexity:569

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=CCCC(=CCCC(=CCCC(=CCSCC(C(=O)OC)N)C)C)C)C
Isomeric SMILES:CC(=CCC/C(=C/CC/C(=C/CC/C(=C/CSC[C@@H](C(=O)OC)N)/C)/C)/C)C

Technology Process of S-[(2E,6E,10E)-3,7,11,15-Tetramethyl-2,6,10,14-hexadecatetrenyl]-L-cysteine methyl ester

There total 1 articles about S-[(2E,6E,10E)-3,7,11,15-Tetramethyl-2,6,10,14-hexadecatetrenyl]-L-cysteine methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.5%

: 7652-46-2
Ac-Cys-OMe

: 136238-12-5
2-amino-3-(3,7,11,15-tetramethyl-hexadeca-2,6,10,14-tetraenylsulfanyl)-propionic acid methyl ester

Guidance literature:: With zinc diacetate; trifluoroacetic acid; In N,N-dimethyl-formamide; acetonitrile; at 20 ℃; for 20h;
DOI:10.1021/ja0119144

Reference yield:

: 136238-12-5
2-amino-3-(3,7,11,15-tetramethyl-hexadeca-2,6,10,14-tetraenylsulfanyl)-propionic acid methyl ester

: 2243-42-7
2-phenoxybenzoic acid

: 1354017-93-8
C₃₇H₄₉NO₄S

Guidance literature:: With benzotriazol-1-ol; O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide; at 0 - 20 ℃;
DOI:10.1016/j.bmc.2011.10.087

Reference yield:

: 136238-12-5
2-amino-3-(3,7,11,15-tetramethyl-hexadeca-2,6,10,14-tetraenylsulfanyl)-propionic acid methyl ester

: 1354017-62-1
(R)-2-(2-phenoxybenzamido)-3-(((2E,6E,10E)-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraen-1-yl)thio)propanoic acid

Guidance literature:: Multi-step reaction with 2 steps

1: benzotriazol-1-ol; O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 0 - 20 °C

2: methanol; lithium hydroxide / 2 h

With methanol; benzotriazol-1-ol; O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine; lithium hydroxide; In N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2011.10.087