(2R,3R,4R,5S)-6-Benzyloxyamino-3-[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-hexane-1,2,4,5-tetraol

Base Information

• Chemical Name: (2R,3R,4R,5S)-6-Benzyloxyamino-3-[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-hexane-1,2,4,5-tetraol
• CAS No.: 129090-66-0
• Molecular Formula: C₂₅H₄₁NO₁₆
• Molecular Weight: 611.598
• Mol file: 129090-66-0.mol

Synonyms:

Chemical Property of (2R,3R,4R,5S)-6-Benzyloxyamino-3-[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-hexane-1,2,4,5-tetraol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2R,3R,4R,5S)-6-Benzyloxyamino-3-[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-hexane-1,2,4,5-tetraol

There total 1 articles about (2R,3R,4R,5S)-6-Benzyloxyamino-3-[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-hexane-1,2,4,5-tetraol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2S,3R,4R,5R)-4-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-2,3,5,6-tetrahydroxy-hexanal O-benzyl-oxime (87978-99-2) → (2R,3R,4R,5S)-6-Benzyloxyamino-3-[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-hexane-1,2,4,5-tetraol (129090-66-0)

Guidance literature:

With pyridine; hydrogenchloride; sodium cyanoborohydride; Yield given. Multistep reaction; methanol;

DOI:10.1016/0008-6215(90)84230-R

Reference yield:

acetic anhydride (108-24-7) + (2R,3R,4R,5S)-6-Benzyloxyamino-3-[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-hexane-1,2,4,5-tetraol (129090-66-0) → N-Benzyloxy-N-{(2S,3R,4R,5R)-4-[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-2,3,5,6-tetrahydroxy-hexyl}-acetamide (129090-70-6)

Guidance literature:

With pyridine; In methanol; for 6h; Ambient temperature;

DOI:10.1016/0008-6215(90)84230-R

upstream raw materials:

(2S,3R,4R,5R)-4-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-2,3,5,6-tetrahydroxy-hexanal O-benzyl-oxime

Downstream raw materials:

N-Benzyloxy-N-{(2S,3R,4R,5R)-4-[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-2,3,5,6-tetrahydroxy-hexyl}-acetamide