(2S-trans)-3-<(Z)-pent-2-enyl>oxirane methanol

Base Information

• Chemical Name: (2S-trans)-3-<(Z)-pent-2-enyl>oxirane methanol
• CAS No.: 133575-33-4
• Molecular Formula: C₈H₁₄O₂
• Molecular Weight: 142.198
• Mol file: 133575-33-4.mol

Synonyms:

Chemical Property of (2S-trans)-3-<(Z)-pent-2-enyl>oxirane methanol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2S-trans)-3-<(Z)-pent-2-enyl>oxirane methanol

There total 3 articles about (2S-trans)-3-<(Z)-pent-2-enyl>oxirane methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

(3-(pent-2-ynyl)oxiran-2-yl)methanol (1408312-99-1) → (Z)-(3-(pent-2-enyl)oxiran-2-yl)methanol (105182-83-0,105228-32-8,129171-46-6,133575-33-4)

Guidance literature:

With hydrogen; In toluene;

DOI:10.1021/jf303395q

Reference yield:

(2E)-2-Octen-5-in-1-ol (81729-08-0) → (Z)-(3-(pent-2-enyl)oxiran-2-yl)methanol (105182-83-0,105228-32-8,129171-46-6,133575-33-4)

Guidance literature:

Multi-step reaction with 2 steps

1: bis(acetylacetonate)oxovanadium; tert.-butylhydroperoxide / toluene / 5 h / 25 °C

2: hydrogen / toluene

With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; hydrogen; In toluene;

DOI:10.1021/jf303395q

Reference yield:

octa-2,5-diyn-1-ol (35378-76-8) → (Z)-(3-(pent-2-enyl)oxiran-2-yl)methanol (105182-83-0,105228-32-8,129171-46-6,133575-33-4)

Guidance literature:

Multi-step reaction with 3 steps

1: lithium aluminium tetrahydride / diethyl ether / 18 h / 0 °C

2: bis(acetylacetonate)oxovanadium; tert.-butylhydroperoxide / toluene / 5 h / 25 °C

3: hydrogen / toluene

With tert.-butylhydroperoxide; lithium aluminium tetrahydride; bis(acetylacetonate)oxovanadium; hydrogen; In diethyl ether; toluene;

DOI:10.1021/jf303395q

upstream raw materials:

(2E)-2-Octen-5-in-1-ol

(3-(pent-2-ynyl)oxiran-2-yl)methanol

octa-2,5-diyn-1-ol

Downstream raw materials:

(Z)-(RS)-1,5-octadien-3-ol

resolvin D3

neuroprotectin D1

(4Z,7Z,10Z,12E,14E,16R,17S,19Z)-16-cysteinyl-17-hydroxy-4,7,10,12,14,19-docosahexaenoic acid