(3R)-3-(prop-1’-en-2’-yl)-hept-6-en-1-yl triisopropylbenzoate

Base Information

Chemical Name:(3R)-3-(prop-1’-en-2’-yl)-hept-6-en-1-yl triisopropylbenzoate
CAS No.:1440278-41-0
Molecular Formula:C₂₆H₄₀O₂
Molecular Weight:384.602
Hs Code.:

Synonyms:

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Chemical Property of (3R)-3-(prop-1’-en-2’-yl)-hept-6-en-1-yl triisopropylbenzoate

Chemical Property:

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Technology Process of (3R)-3-(prop-1’-en-2’-yl)-hept-6-en-1-yl triisopropylbenzoate

There total 2 articles about (3R)-3-(prop-1’-en-2’-yl)-hept-6-en-1-yl triisopropylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1440278-37-4
(3R)-3-(prop-1’-en-2’-yl)-6-tosyloxyhept-1-yl triisopropylbenzoate

: C₂₆H₄₀O₂

: 1440278-41-0
(3R)-3-(prop-1’-en-2’-yl)-hept-6-en-1-yl triisopropylbenzoate

Guidance literature:: With potassium tert-butylate; In hexane; at 20 ℃; for 7h; Overall yield = 96 %; Overall yield = 667 mg; regioselective reaction;
DOI:10.1002/anie.201207312

Reference yield:

: (3R)-3-(prop-1’-en-2’-yl)-heptan-1,6-diol

: 1440278-41-0
(3R)-3-(prop-1’-en-2’-yl)-hept-6-en-1-yl triisopropylbenzoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydride / tetrahydrofuran; mineral oil / 0.67 h / 0 - 20 °C / Inert atmosphere; Schlenk technique

1.2: 48 h / Inert atmosphere; Schlenk technique; Reflux

2.1: triethylamine; dmap / dichloromethane / 24 h / 20 °C

3.1: potassium tert-butylate / hexane / 7 h / 20 °C

With dmap; potassium tert-butylate; sodium hydride; triethylamine; In tetrahydrofuran; hexane; dichloromethane; mineral oil;
DOI:10.1002/anie.201207312

Reference yield:

: 1440278-41-0
(3R)-3-(prop-1’-en-2’-yl)-hept-6-en-1-yl triisopropylbenzoate

: 67225-47-2,64309-04-2
(3Z,6R)-3-methyl-6-(1-methylethenyl)-3,9-decadien-1-yl acetate

Guidance literature:: Multi-step reaction with 3 steps

1.1: sec.-butyllithium; N,N,N,N,-tetramethylethylenediamine / diethyl ether / 4 h / -78 °C / Inert atmosphere; Schlenk technique

1.2: 17 h / -78 - 45 °C / Inert atmosphere; Schlenk technique; Enzymatic reaction

2.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 18 h / 20 - 45 °C / Inert atmosphere; Schlenk technique

3.1: pyridine / 1.5 h / 0 - 20 °C / Inert atmosphere; Schlenk technique

With pyridine; N,N,N,N,-tetramethylethylenediamine; tetrabutyl ammonium fluoride; sec.-butyllithium; In tetrahydrofuran; diethyl ether;
DOI:10.1002/anie.201207312