trans-4-chlorostilbene radical cation

Base Information

• Chemical Name: trans-4-chlorostilbene radical cation
• CAS No.: 130059-92-6
• Molecular Formula: C₁₄H₁₁Cl
• Molecular Weight: 214.694
• Mol file: 130059-92-6.mol

Synonyms:

Chemical Property of trans-4-chlorostilbene radical cation

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of trans-4-chlorostilbene radical cation

There total 65 articles about trans-4-chlorostilbene radical cation which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

4-vinylbenzyl chloride (1073-67-2,24991-47-7) + iodobenzene (591-50-4) → 1-chloro-4-styrylbenzene (1657-49-4,1657-50-7,4714-23-2,130059-92-6,130059-96-0)

Guidance literature:

With tetrabutyl ammonium fluoride; palladium diacetate; potassium carbonate; at 70 ℃; for 36h; air;

DOI:10.1055/s-0031-1290099

Reference yield: 99.0%

benzylidene dichloride (98-87-3) + 4-chlorobenzaldehyde (104-88-1) → 1-chloro-4-styrylbenzene (1657-49-4,1657-50-7,4714-23-2,130059-92-6,130059-96-0)

Guidance literature:

With chloro-trimethyl-silane; zinc; In tetrahydrofuran; at 50 ℃; for 3h;

DOI:10.1246/bcsj.71.2669

Reference yield: 97.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + bromochlorobenzene (106-39-8) → 1-chloro-4-styrylbenzene (1657-49-4,1657-50-7,4714-23-2,130059-92-6,130059-96-0)

Guidance literature:

With tributyl-amine; tetrabutylammomium bromide; In neat (no solvent); at 110 ℃; for 6h; Inert atmosphere;

DOI:10.1007/s10562-013-1013-7

upstream raw materials:

cinnamic acid 4-chlorophenyl ester

(E)-3-(4-chlorophenyl)acrylic acid phenyl ester

styrene

bromochlorobenzene

Downstream raw materials:

4-{(E)-2-[4-((E)-Styryl)-phenyl]-vinyl}-benzonitrile

(±)-2-(4-chlorophenyl)-3-phenylpropanoic acid

(±)-3-(4-chlorophenyl)-2-phenylpropanoic acid

4-chlorobibenzyl