Technology Process of 6α,7α-cyclopropano-5α-androstane-3α,17β-diol 17-benzoate
There total 9 articles about 6α,7α-cyclopropano-5α-androstane-3α,17β-diol 17-benzoate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 82 percent / Br2 / CHCl3 / 0.33 h / Ambient temperature
2: 102 mg / Zn / acetic acid / Heating
3: 182 mg / Zn-Cu, perphthalic acid / diethyl ether / 7 h / 100 °C
4: 720 mg / conc. aq. HCl / CHCl3; methanol / 20 h / 22 °C
5: 260 mg / Jones' reagent / acetone / 0.17 h
6: 8.5 mg / lithium tri-tert-butoxyaluminium hydride / ethyl acetate / 0.17 h / Ambient temperature
With
hydrogenchloride; jones' reagent; dioxyphthalic acid; lithium tri(t-butoxy)aluminum hydride; bromine; copper; zinc;
In
methanol; diethyl ether; chloroform; acetic acid; ethyl acetate; acetone;
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 18 mg / NaBH4 / methanol
2: 43 mg / Zn / acetic acid / 6 h / Heating
3: 182 mg / Zn-Cu, perphthalic acid / diethyl ether / 7 h / 100 °C
4: 720 mg / conc. aq. HCl / CHCl3; methanol / 20 h / 22 °C
5: 260 mg / Jones' reagent / acetone / 0.17 h
6: 8.5 mg / lithium tri-tert-butoxyaluminium hydride / ethyl acetate / 0.17 h / Ambient temperature
With
hydrogenchloride; sodium tetrahydroborate; jones' reagent; dioxyphthalic acid; lithium tri(t-butoxy)aluminum hydride; copper; zinc;
In
methanol; diethyl ether; chloroform; acetic acid; ethyl acetate; acetone;
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 720 mg / conc. aq. HCl / CHCl3; methanol / 20 h / 22 °C
2: 260 mg / Jones' reagent / acetone / 0.17 h
3: 8.5 mg / lithium tri-tert-butoxyaluminium hydride / ethyl acetate / 0.17 h / Ambient temperature
With
hydrogenchloride; jones' reagent; lithium tri(t-butoxy)aluminum hydride;
In
methanol; chloroform; ethyl acetate; acetone;
