(1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

Base Information

Chemical Name:(1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene
CAS No.:636603-08-2
Molecular Formula:C₄₂H₆₄O₂Si₂
Molecular Weight:657.14
Hs Code.:

(1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

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Chemical Property of (1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

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Technology Process of (1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

There total 10 articles about (1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 636603-04-8
8-(tert-butyl-dimethyl-silanyloxymethyl)-12-(tert-butyl-diphenyl-silanyloxymethyl)-4-methyl-11-(3-oxo-butyl)-trideca-4,8,12-trienal

: 636603-08-2
(1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

Guidance literature:: With pyridine; titanium tetrachloride; zinc; In 1,2-dimethoxyethane; Heating;
DOI:10.1055/s-2003-42077

Reference yield:

: 10067-33-1
(S)-(-)-p-mentha-1,8⁽¹⁰⁾-dien-9-ol

: 636603-08-2
(1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

Guidance literature:: Multi-step reaction with 8 steps

1.1: imidazole / dimethylformamide

2.1: O₃ / CH₂Cl₂ / -78 °C

2.2: Me₂S / CH₂Cl₂

3.1: n-BuLi / tetrahydrofuran / -78 °C

4.1: DIBALH / CH₂Cl₂ / -78 °C

5.1: imidazole / dimethylformamide

6.1: MgBr₂ / diethyl ether / 20 °C

7.1: TiCl₄; Zn; pyridine / 1,2-dimethoxy-ethane / Heating

With pyridine; 1H-imidazole; n-butyllithium; titanium tetrachloride; diisobutylaluminium hydride; ozone; magnesium bromide; zinc; In tetrahydrofuran; 1,2-dimethoxyethane; diethyl ether; dichloromethane; N,N-dimethyl-formamide; 3.1: Horner-Emmons coupling / 7.1: Swern oxidation;
DOI:10.1055/s-2003-42077

Reference yield:

: 5989-54-8,555-08-8,8022-90-0,9003-73-0,95327-98-3
(-)-(S)-limonene

: 636603-08-2
(1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

Guidance literature:: Multi-step reaction with 9 steps

1.1: n-BuLi; TMEDA / tetrahydrofuran / 24 h / 23 °C

1.2: O₂ / tetrahydrofuran

2.1: imidazole / dimethylformamide

3.1: O₃ / CH₂Cl₂ / -78 °C

3.2: Me₂S / CH₂Cl₂

4.1: n-BuLi / tetrahydrofuran / -78 °C

5.1: DIBALH / CH₂Cl₂ / -78 °C

6.1: imidazole / dimethylformamide

7.1: MgBr₂ / diethyl ether / 20 °C

8.1: TiCl₄; Zn; pyridine / 1,2-dimethoxy-ethane / Heating

With pyridine; 1H-imidazole; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride; diisobutylaluminium hydride; ozone; magnesium bromide; zinc; In tetrahydrofuran; 1,2-dimethoxyethane; diethyl ether; dichloromethane; N,N-dimethyl-formamide; 4.1: Horner-Emmons coupling / 8.1: Swern oxidation;
DOI:10.1055/s-2003-42077