trans-(triphenylphosphine)2Pt(CO)Cl⁽¹⁺⁾

Base Information

• Chemical Name: trans-(triphenylphosphine)2Pt(CO)Cl⁽¹⁺⁾
• CAS No.: 20683-70-9
• Molecular Formula: C₃₇H₃₀ClOP₂Pt
• Molecular Weight: 783.125
• Mol file: 20683-70-9.mol

Synonyms:

Chemical Property of trans-(triphenylphosphine)2Pt(CO)Cl⁽¹⁺⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-(triphenylphosphine)2Pt(CO)Cl⁽¹⁺⁾

There total 3 articles about trans-(triphenylphosphine)2Pt(CO)Cl⁽¹⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tin(II) chloride dihdyrate (10025-69-1) + cis-triphenylphosphinecarbonylplatinum(II) dichloride (22585-09-7,73347-20-3,19618-78-1) → pentakis(trichlorostannyl(II))-platinate(II)(2-) + trans-(triphenylphosphine)2Pt(CO)Cl(1+) (20683-70-9,32424-72-9,74924-19-9) + trans-[PtCl(SnCl3)2(P(C6H5)3)](1-) (83719-70-4)

Guidance literature:

In [⁽²⁾H₆]acetone; acetone; Pt complex mixed with 5.0 equiv of SnCl2*2H2O, solvents added, shook until clear soln. formed; not isolated, monitored by NMR;

Reference yield:

tin(II) chloride dihdyrate (10025-69-1) + cis-triphenylphosphinecarbonylplatinum(II) dichloride (22585-09-7,73347-20-3,19618-78-1) → trans-(triphenylphosphine)2Pt(CO)Cl(1+) (20683-70-9,32424-72-9,74924-19-9)

Guidance literature:

In [D₃]acetonitrile; acetonitrile; Pt complex mixed with 2.0 equiv of SnCl2*2H2O, solvents added, shook until clear soln. formed; not isolated, monitored by NMR;

Reference yield:

tin(II) chloride dihdyrate (10025-69-1) + cis-triphenylphosphinecarbonylplatinum(II) dichloride (22585-09-7,73347-20-3,19618-78-1) + (PtCl2(CO)P(C6H4F)3) (76705-01-6) → trans-(triphenylphosphine)2Pt(CO)Cl(1+) (20683-70-9,32424-72-9,74924-19-9) + trans-[PtCl(CO)(P(C6H5)3)(P(p-FC6H4)3)](1+) (83731-23-1) + trans-[PtCl(CO)(P(p-FC6H4)3)2](1+) (83721-22-6)

Guidance literature:

In [⁽²⁾H₆]acetone; acetone; 2.0 equiv of SnCl2*2H2O added to equimolar mixt. of Pt complexes, solvents added, shook at 25°C until clear soln. formed; not isolated, monitored by NMR;

upstream raw materials:

tin(II) chloride dihdyrate

cis-triphenylphosphinecarbonylplatinum(II) dichloride

(PtCl₂(CO)P(C₆H₄F)3)

Downstream raw materials:

cis-[PtBr₂(PPh₃)2]

Refernces

• 1、 Anderson, Gordon K.,Clark, Howard C.,Davies, Julian A.. "Role of the trichlorostannyl ligand in homogeneous catalysis. 3. Solvent effects on the reactions of cis-[PtCl2(L)(PR3)] and [Pt2(μ-Cl)2Cl2(PR3)2] (L = CO, SMe2; R = Ph, Et) with SnCl2·2H2O". . p. 434 - 438. Retrieved 2008/10/08.