2,4,6-tri-t-butylphenyl-hydroxy-trimethylsilylaminoborane

Base Information

• Chemical Name: 2,4,6-tri-t-butylphenyl-hydroxy-trimethylsilylaminoborane
• CAS No.: 129161-79-1
• Molecular Formula: C₂₁H₄₀BNOSi
• Molecular Weight: 361.451
• Mol file: 129161-79-1.mol

Synonyms:

Chemical Property of 2,4,6-tri-t-butylphenyl-hydroxy-trimethylsilylaminoborane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,4,6-tri-t-butylphenyl-hydroxy-trimethylsilylaminoborane

There total 3 articles about 2,4,6-tri-t-butylphenyl-hydroxy-trimethylsilylaminoborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

2,4,6-tri-t-butylphenyl-trimethylsilyliminoborane (129161-72-4) + water (7732-18-5) → 2,4,6-tri-t-butylphenyl-hydroxy-trimethylsilylaminoborane (129161-79-1)

Guidance literature:

In hexane; H2O added dropwise to a soln. of the iminoborane, heated for 3 h under reflux; solvent removed in vac., sublimed (0.01 mbar); elem. anal.;

DOI:10.1016/0022-328X(90)80060-D

Reference yield:

2,4,6-tri-tert-butylphenyllithium (35383-91-6) → 2,4,6-tri-t-butylphenyl-hydroxy-trimethylsilylaminoborane (129161-79-1)

Guidance literature:

Multi-step reaction with 3 steps

1: petroleum ether

2: neat (no solvent)

3: hexane

In hexane;

DOI:10.1016/0022-328X(90)80060-D

Reference yield:

2,4,6-tri-t-butylphenyl-fluoro-{bis(trimethylsilyl)amino}-borane (129161-70-2) → 2,4,6-tri-t-butylphenyl-hydroxy-trimethylsilylaminoborane (129161-79-1)

Guidance literature:

Multi-step reaction with 2 steps

1: neat (no solvent)

2: hexane

In hexane;

DOI:10.1016/0022-328X(90)80060-D

upstream raw materials:

2,4,6-tri-t-butylphenyl-trimethylsilyliminoborane

water

2,4,6-tri-t-butylphenyl-fluoro-{bis(trimethylsilyl)amino}-borane

2,4,6-tri-tert-butylphenyllithium