ReOCl3(triphenylarsine)2

Base Information

Chemical Name:ReOCl3(triphenylarsine)2
CAS No.:87863-04-5
Molecular Formula:C₃₆H₃₀As₂Cl₃ORe
Molecular Weight:921.043
Hs Code.:

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Chemical Property of ReOCl3(triphenylarsine)2

Chemical Property:

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Technology Process of ReOCl3(triphenylarsine)2

There total 2 articles about ReOCl3(triphenylarsine)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 10466-65-6
potassium perrhenate

: 603-32-7
triphenyl-arsane

: 87863-04-5,608133-96-6
ReOCl3(triphenylarsine)2

Guidance literature:: With hydrogenchloride; In hydrogenchloride; acetic acid; addn. of As(C6H5)3 (20.9 mmol) to suspension of KReO4 (6.91 mmol) in glacial acetic acid and concd. HCl (28.0 mmol); stirring vigorously at room temp. for 5 h;; pptn.; filtering off, washing with glacial acetic acid and (C2H5)2O, drying in vac.; elem. anal.;;

Reference yield: 74.0%

: rhenium

: 603-32-7
triphenyl-arsane

: 87863-04-5,608133-96-6
ReOCl3(triphenylarsine)2

Guidance literature:: With H₂O₂; HCl; In acetic acid; Re dissolved in H2O2, evapd., dissolved in concd. HCl, addn. of AsPh3 soln., stirred for 30 min;; ppt. filtered, washed with Et2O, dried in vac.;;
DOI:10.1039/DT9910001519

Reference yield: 98.0%

: 87863-04-5,608133-96-6
ReOCl3(triphenylarsine)2

: 141547-34-4
N,N-bis(2-(diphenylphosphanyl)ethyl)phenylamine

: {bis(2-diphenylphosphinoethyl)phenylamine}trichlorooxorhenium(V)

Guidance literature:: In dichloromethane; stirring soln. of Re-complex and ligand at room temp. for 3 h (N2); concn. (vac.), addn. of Et2O and hexane, pptn., filtration, washing (Et2O), drying (vac.); elem. anal.;
DOI:10.1039/DT9920001735