nickel(II) bis(2-mercaptophenyl)sulfide NHPCy₃

Base Information

• Chemical Name: nickel(II) bis(2-mercaptophenyl)sulfide NHPCy₃
• CAS No.: 828919-08-0
• Molecular Formula: C₃₀H₄₂NNiPS₃
• Molecular Weight: 602.532

Synonyms:

Chemical Property of nickel(II) bis(2-mercaptophenyl)sulfide NHPCy₃

Chemical Property:

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Technology Process of nickel(II) bis(2-mercaptophenyl)sulfide NHPCy₃

There total 1 articles about nickel(II) bis(2-mercaptophenyl)sulfide NHPCy₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

tri[nickel(II) bis(2-mercaptophenyl)sulfide] + 1,1,1-tricyclohexyl-N-(trimethylsilyl)-λ5-phosphanimine (182060-48-6) → nickel(II) bis(2-mercaptophenyl)sulfide NHPCy3 (828919-08-0)

Guidance literature:

In tetrahydrofuran; methanol; (N2, at room temp.), ligand in THF and MeOH added to a suspn. of Ni complex in THF, reacted for 15 h; evapd., redissolved (THF), filtered,, concd., layered with CH3CN, pptd. at -25°C for 3 d, washed (cold CH3CN, Et2O), dried (vac.), elem. anal.;

DOI:10.1002/ejic.200300786

Reference yield:

nickel(II) bis(2-mercaptophenyl)sulfide NHPCy3 (828919-08-0) + deuterium (16873-17-9,12184-84-8) → nickel(II) bis(2-mercaptophenyl)sulfide NDPCy3

Guidance literature:

In tetrahydrofuran-d8; water; byproducts: HD; High Pressure; (in a high pressure NMR tube), concd. soln. of Ni complex in THF-d8 treated with H2O, pressurized with 18 bar of D2 for 80-120 h; not isolated, detected by NMR;

DOI:10.1002/ejic.200300786

Reference yield:

d(4)-methanol (811-98-3) + nickel(II) bis(2-mercaptophenyl)sulfide NHPCy3 (828919-08-0) → nickel(II) bis(2-mercaptophenyl)sulfide NDPCy3

Guidance literature:

In dichloromethane; byproducts: H(+); (N2, at room temp.), CD3OD added in NMR tube to sat. soln. of Ni complexin CH2Cl2, reacted for 5-20 min; evapd.(vac.), IR;

DOI:10.1002/ejic.200300786

upstream raw materials:

1,1,1-tricyclohexyl-N-(trimethylsilyl)-λ⁵-phosphanimine

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