a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)palladium

Base Information

• Chemical Name: a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)palladium
• CAS No.: 1145982-26-8
• Molecular Formula: C₂₉H₂₃ClNPPd
• Molecular Weight: 558.355
• Mol file: 1145982-26-8.mol

Synonyms:

Chemical Property of a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)palladium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)palladium

There total 2 articles about a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)palladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

bis[(2-phenylpyridinato-C(2'),N(1))(μ-chlorido)palladium(II)] + triphenylphosphine (603-35-0) → a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)palladium (1145982-26-8,76857-95-9)

Guidance literature:

In chloroform; treatment of (Pd(Cl)(2-phenylpyridine))2 with PPh3 in CHCl3 at toom temp. according to: G. L. Edwards, C.D. St. Black, G.B. Deacon, L.P.G. Wakelin, Can. J. Chem. 83 (2005) 980; M.A. Gutierrez, G. R. Newkome, J. Selbin, J. Organomet. Chem. 202 (1980) 341;

DOI:10.1016/j.jorganchem.2008.11.065

Reference yield:

2-phenylpyridine (1008-89-5) → a-chloro-dc-[2-(2'-pyridyl)phenyl-N',C]-b-(triphenylphosphine)palladium (1145982-26-8,76857-95-9)

Guidance literature:

Multi-step reaction with 2 steps

1: not given

2: chloroform

In chloroform;

DOI:10.1016/j.jorganchem.2008.11.065

upstream raw materials:

triphenylphosphine

2-phenylpyridine