Technology Process of syn,syn-1,5,9-triphenyl-1,5,9-triphosphacyclododecane
There total 1 articles about syn,syn-1,5,9-triphenyl-1,5,9-triphosphacyclododecane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
rac-allyl(phenyl)phosphine;
With
benzene(cyclopentadienyl)iron(II) hexafluorophosphate;
In
dichloromethane;
Irradiation;
With
2,2'-azobis(isobutyronitrile);
In
chlorobenzene;
at 90 ℃;
With
ammonia; sodium;
Further stages.;
DOI:10.1039/b002174l
- Guidance literature:
-
In
tetrahydrofuran;
Irradiation (UV/VIS); (N2); a soln. of ligand added to a soln. of Fe complex, irradiated with UV for 8 h; evapd. (vac.), recrystd. (MeCN/Et2O);
DOI:10.1039/b509627h
- Guidance literature:
-
In
hexane; dichloromethane;
under N2; to a suspn. of Cr complex in CH2Cl2 was added a soln. of the ligand in hexane, the mixt. was stirred for 12 h; the mixt. was filtered, soln. was evapd. in vac., the residue was triturated with hexane, the solid was extd. into warm CH2Cl2, soln. was concd., cooled to -30°C, the solid was filtered, washed with hexane, dried in vac.; elem. anal.;
DOI:10.1039/b203002k
