Technology Process of cobalt 2-vinyl-5,10,15,20-tetraphenylporphyrinate
There total 2 articles about cobalt 2-vinyl-5,10,15,20-tetraphenylporphyrinate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
chloroform; acetic acid;
addn. of cobalt acetate in acetic acid to soln. of porphyrin deriv. in CHCl3, refluxing for 30 min; cooling, washing with water, concn., addn. of boiling methanol, cooling,filtration, washing with methanol, water and methanol, drying at 110.de gree.C;
DOI:10.1007/s11172-007-0026-z
- Guidance literature:
-
With
18-crown-6 ether; potassium carbonate;
In
benzene;
(Ar); refluxing mixt. of cobalt compd., triphenylmethylphosphonium salt,potassium carbonate and 18-crown-6 in anhydrous benzene for 10 h; cooling, filtration through Al2O3, concn., chromy. (silica gel, benzene), evapn., recrystn. (CHCl3-methanol (1:3)), elem. anal.;
DOI:10.1007/s11172-007-0026-z
