chromium (3-(chloromethyl)phenyl)methoxycarbene pentacarbonyl complex

Base Information

Chemical Name:chromium (3-(chloromethyl)phenyl)methoxycarbene pentacarbonyl complex
CAS No.:27436-98-2
Molecular Formula:C₁₄H₉ClCrO₆
Molecular Weight:360.671
Hs Code.:

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Chemical Property of chromium (3-(chloromethyl)phenyl)methoxycarbene pentacarbonyl complex

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Technology Process of chromium (3-(chloromethyl)phenyl)methoxycarbene pentacarbonyl complex

There total 1 articles about chromium (3-(chloromethyl)phenyl)methoxycarbene pentacarbonyl complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.4%

: 109283-12-7
lithium pentacarbonylchromate

: 63024-77-1
3-(Chloromethyl)benzoyl chloride

: 420-37-1
trimethoxonium tetrafluoroborate

: 27436-98-2
chromium (3-(chloromethyl)phenyl)methoxycarbene pentacarbonyl complex

Guidance literature:: In tetrahydrofuran; water; byproducts: LiCl, Li{BF4}, Me2O; under Ar freshly prepd. soln. of Li2(Cr(CO)5) in THF added at -78°C to acyl chloride in THF, solvent removed in vac., residue suspended in H2O(4°C), solid (Me3O)BF4 added in single portion, warmed to 25°C; after 5 min extd. with n-hexane, dried over anhyd. Na2SO4, concd. in vac., flash chromd. (SiO2, 4:1 n-hexane/CH2Cl2), evapd. in vac., recrystd. from n-pentane at temp. below -20°C;
DOI:10.1021/om00152a002