N,N'-bis-(2-(4-methoxybenzylthio)-2-methylpropyl)propane-1,3-diamine

Base Information

• Chemical Name: N,N'-bis-(2-(4-methoxybenzylthio)-2-methylpropyl)propane-1,3-diamine
• CAS No.: 1258542-50-5
• Molecular Formula: C₂₇H₄₂N₂O₂S₂
• Molecular Weight: 490.775
• Mol file: 1258542-50-5.mol

Synonyms:

Chemical Property of N,N'-bis-(2-(4-methoxybenzylthio)-2-methylpropyl)propane-1,3-diamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-bis-(2-(4-methoxybenzylthio)-2-methylpropyl)propane-1,3-diamine

There total 1 articles about N,N'-bis-(2-(4-methoxybenzylthio)-2-methylpropyl)propane-1,3-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2'-dithiobis(2-methylpropanal) (15581-80-3) → N,N'-bis-(2-(4-methoxybenzylthio)-2-methylpropyl)propane-1,3-diamine (1258542-50-5)

Guidance literature:

Multi-step reaction with 3 steps

1: benzene / 8 h / Reflux

2: lithium aluminium tetrahydride / tetrahydrofuran / 12 h / Reflux

3: sodium hydroxide / ethanol; water / 1 h

With lithium aluminium tetrahydride; sodium hydroxide; In tetrahydrofuran; ethanol; water; benzene;

DOI:10.1039/c0dt00813c

Reference yield: 35.0%

ammonium hexafluorophosphate + rhodium(III) trichloride hydrate + N,N'-bis-(2-(4-methoxybenzylthio)-2-methylpropyl)propane-1,3-diamine (1258542-50-5) → cis/trans-[dichloro(N,N'-bis-(2-(4-methoxybenzylthio)-2-methylpropyl)propane-1,2-diamine)rhodium(III)] hexafluorophosphate (1258542-55-0,1258788-81-6)

Guidance literature:

With NaOH; In ethanol; water; soln. of RhCl3*xH2O in 20 % aq. EtOH was added to aq. soln. of ligand, pH was adjusted to approx. 5 by addition of 2.5 M NaOH, heated at 80°C for 1 h, centrifuged, soln. was concd in vac., satd. aq. NH4PF6 wasadded; precipitate was centrifuged, washed with water, EtOH and Et2O, dried in vac.;

DOI:10.1039/c0dt00813c

Reference yield:

N,N'-bis-(2-(4-methoxybenzylthio)-2-methylpropyl)propane-1,3-diamine (1258542-50-5) → N,N'-bis(2-(4-methoxybenzylthio)-2-methylpropyl)propane-1,3-diamine dihydrochloride

Guidance literature:

With hydrogenchloride; In ethanol; at 20 ℃; pH=2 - 3;

DOI:10.1039/c0dt00813c

upstream raw materials:

2,2'-dithiobis(2-methylpropanal)

Downstream raw materials:

cis/trans-[dichloro(N,N'-bis-(2-(4-methoxybenzylthio)-2-methylpropyl)propane-1,2-diamine)rhodium(III)] hexafluorophosphate

cis/trans-[⁽¹⁰⁵⁾RhCl₂(N,N'-bis-(2-(4-methoxybenzylthio)-2-methylpropyl)propane-1,3-diamine)]PF₆

Refernces