trans-dichloro(C-meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)ruthenium(III) p-toluenesulfonate

Base Information

• Chemical Name: trans-dichloro(C-meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)ruthenium(III) p-toluenesulfonate
• CAS No.: 76740-66-4
• Molecular Formula: C₇H₇O₃S*C₁₆H₃₆Cl₂N₄Ru
• Molecular Weight: 627.661
• Mol file: 76740-66-4.mol

Synonyms:

Chemical Property of trans-dichloro(C-meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)ruthenium(III) p-toluenesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-dichloro(C-meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)ruthenium(III) p-toluenesulfonate

There total 1 articles about trans-dichloro(C-meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)ruthenium(III) p-toluenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (10368-90-8) + potassium aquapentachlororuthenate(III) + toluene-4-sulfonic acid (104-15-4) → trans-dichloro(C-meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)ruthenium(III) p-toluenesulfonate (76740-66-4)

Guidance literature:

In ethanol; in inert atm. suspn. K2(RuCl5(H2O)) in ethanol heated under reflux and with stirring for 15 min, ethanolic soln. teta added dropwise and refluxed overnight, soln. filtered while hot, p-toluenesulfonic acid added; soln. evapd. to dryness, solid recrystd. from hot dilute p-toluenesulfonic acid, crystals collected, washed with abs. ethanol and ether and dried in vacuo at 78°C; elem. anal.;

DOI:10.1021/ic50220a004

upstream raw materials:

meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane

toluene-4-sulfonic acid