[Rh₂(CH₃CO₂)3(H₂O)4]⁽¹⁺⁾*ClO₄^(1-)=[Rh₂(CH₃CO₂)3(H₂O)4]ClO₄

Base Information

• Chemical Name: [Rh₂(CH₃CO₂)3(H₂O)4]⁽¹⁺⁾*ClO₄^(1-)=[Rh₂(CH₃CO₂)3(H₂O)4]ClO₄
• CAS No.: 106564-52-7
• Molecular Formula: C₆H₁₇O₁₀Rh₂*ClO₄
• Molecular Weight: 554.457
• Mol file: 106564-52-7.mol

Synonyms:

Chemical Property of [Rh₂(CH₃CO₂)3(H₂O)4]⁽¹⁺⁾*ClO₄^(1-)=[Rh₂(CH₃CO₂)3(H₂O)4]ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [Rh₂(CH₃CO₂)3(H₂O)4]⁽¹⁺⁾*ClO₄^(1-)=[Rh₂(CH₃CO₂)3(H₂O)4]ClO₄

There total 1 articles about [Rh₂(CH₃CO₂)3(H₂O)4]⁽¹⁺⁾*ClO₄^(1-)=[Rh₂(CH₃CO₂)3(H₂O)4]ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

dirhodium tetraacetate + barium perchlorate trihydrate → dirhodium tetracetate dihydrate (917499-87-7,29998-99-0) + [Rh2(CH3CO2)2(H2O)6](2+)*2ClO4(1-)=[Rh2(CH3CO2)2(H2O)6](ClO4)2 + [Rh2(CH3CO2)3(H2O)4](1+)*ClO4(1-)=[Rh2(CH3CO2)3(H2O)4]ClO4 (106564-52-7)

Guidance literature:

With H₂SO₄; In sulfuric acid; byproducts: BaSO4, KClO4; aq. H2SO4; react. of (Rh2(CH3CO2)4) with H2SO4 (molar ratio 1:2); dissolving product in boiling H2O under Ar; addn. of excess Ba(ClO4)2*3H2O with stirring; cooling, filtering off ppt. of BaSO4; evapg. filtrate to min. vol. and passing through ion exchange column;; elution with H2O, 0.05 M and 0.5 M HClO4; adjusting HClO4-eluates to pH7 with aq. KOH-soln. (Ar), filtering, evapg. to dryness and drying in vac. desiccator (P2O5); dissolving in min. of abs. C2H5OH, filtering and evapg. to dryness; elem. anal.;;