trans-vinyl(triphenylsilyl)bis(dimethylphenylphosphine)platinum(II)

Base Information

Chemical Name:trans-vinyl(triphenylsilyl)bis(dimethylphenylphosphine)platinum(II)
CAS No.:853400-90-5
Molecular Formula:C₃₆H₄₀P₂PtSi
Molecular Weight:757.827
Hs Code.:

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Chemical Property of trans-vinyl(triphenylsilyl)bis(dimethylphenylphosphine)platinum(II)

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Technology Process of trans-vinyl(triphenylsilyl)bis(dimethylphenylphosphine)platinum(II)

There total 1 articles about trans-vinyl(triphenylsilyl)bis(dimethylphenylphosphine)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 31388-57-5,25930-50-1,26709-54-6
trans-chloro(triphenylsilyl)bis(dimethylphenylphosphine)platinum(II)

: 6928-74-1
divinylmagnesium

: 211870-72-3,853400-90-5
trans-vinyl(triphenylsilyl)bis(dimethylphenylphosphine)platinum(II)

Guidance literature:: In tetrahydrofuran; diethyl ether; under N2; soln. of Mg(CHCH2)2 in Et2O added to soln. of Pt complex in THF; stirred at room temp. for 30 min; cooled to -30°C; MeOH added slowly; concd. to dryness under vac.;extd. with benzene; filtered (Celite); concd. to dryness; washed (hexan e-Et2O); dried under vac.; crystd. from CH2Cl2 layered with hexane at -70°C; elem. anal.;
DOI:10.1021/om0580001

Reference yield:

: 211870-72-3,853400-90-5
trans-vinyl(triphenylsilyl)bis(dimethylphenylphosphine)platinum(II)

: 853268-48-1
(vinyltriphenylsilane)bis(dimethylphenylphosphine)platinum⁽⁰⁾

Guidance literature:: With carbon monoxide; Dimethyl(phenyl)phosphine; In ⁽²⁾H₈-toluene; under N2; Pt complex dissolved in toluene-d8 at room temp.; evacuated at-70°C; filled with CO (1 atm); stirred at -30°C for 1 h; CO removed at -70°C under vac.; replaced with N2 (1 atm); kept at 25°C in presence of PMe2Ph; not isolated; monitored by (1)H, (13)C and (31)P NMR spectra; Kinetics;
DOI:10.1021/om0580001

Reference yield:

: 211870-72-3,853400-90-5
trans-vinyl(triphenylsilyl)bis(dimethylphenylphosphine)platinum(II)

: cis-vinyl(triphenylsilyl)bis(dimethylphenylphosphine)platinum(II)

Guidance literature:: With carbon monoxide; In dichloromethane-d2; under N2; Pt complex dissolved in CD2Cl2; evacuated; placed under CO (1 atm) at -70°C; stirred at -30°C for 1 h; CO removed under vac. at -70°C; N2 introduced; not isolated; detd. by (1)H, (13)C, (195)Pt and (31)P NMR spectra;
DOI:10.1021/om0580001