[5-bromo-10,20-diphenyl-15-(4'-methoxyphenyl)porphinato]zinc

Base Information

Chemical Name:[5-bromo-10,20-diphenyl-15-(4'-methoxyphenyl)porphinato]zinc
CAS No.:178119-54-5
Molecular Formula:C₃₉H₂₅BrN₄OZn
Molecular Weight:710.948
Hs Code.:

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Chemical Property of [5-bromo-10,20-diphenyl-15-(4'-methoxyphenyl)porphinato]zinc

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Technology Process of [5-bromo-10,20-diphenyl-15-(4'-methoxyphenyl)porphinato]zinc

There total 1 articles about [5-bromo-10,20-diphenyl-15-(4'-methoxyphenyl)porphinato]zinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

: 104-92-7
1-bromo-4-methoxy-benzene

: 147470-60-8
[5,10-dibromo-10,20-bis-(phenyl)porphyrinato^(2-)]zinc

: 178119-54-5
[5-bromo-10,20-diphenyl-15-(4'-methoxyphenyl)porphinato]zinc

: 866959-10-6
[5,15-bis(4'-methoxyphenyl)-10,20-diphenylporphinato]zinc

Guidance literature:: With n-butyllithium; zinc(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; N2-atmosphere; addn. of 1 equiv. BuLi (in hexanes) to BrC6H4OMe (in THF)at -78°C, then addn. of ZnCl2 (after 10 min), warming to room te mp., add. of excess Zn-porphyrin and catalyst, standing for 6 h (TLC control); addn. to satd. aq. NaHCO3, extn. into CHCl3, drying (CaCl2), evapn., treatment with N-bromosuccinimide (in CHCl3, 0°C), chromy. (SiO2, hexane/THF=10:1), recrystn. (THF/hexane); elem. anal.;

Reference yield: 8.0%

: trans,trans-3,7-bis(4',4''-trimethyltinphenyl)-cis-bicyclo[3.3.0]octane

: 178119-54-5
[5-bromo-10,20-diphenyl-15-(4'-methoxyphenyl)porphinato]zinc

: [Zn(C₂₀H₈N₄(C₆H₅)2(C₆H₄OCH₃))]2[C₈H₁₂(C₆H₄)2]

Guidance literature:: (1,1'-bis(diphenylphosphine)ferrocene)palladium⁽⁰⁾; In tetrahydrofuran; N2-atmosphere; stoich. amts., 5% catalyst, in THF/N-methylpyrrolidinone=19:1, 60°C, 4 weeks; solvent removal (reduced pressure), chromy. (SiO2, THF/hexane=10:1, then7:3), HPLC (Raining Dynamac Si, CHCl3/hexane=7:3);

Reference yield: 6.0%

: 3,7-bis(4',4''-trimethyltinphenyl)-cis-bicyclo[3.3.0]octa-2,6-diene

: 178119-54-5
[5-bromo-10,20-diphenyl-15-(4'-methoxyphenyl)porphinato]zinc

: [Zn(C₂₀H₈N₄(C₆H₅)2(C₆H₄OCH₃))]2[C₈H₈(C₆H₄)2]

Guidance literature:: (1,1'-bis(diphenylphosphine)ferrocene)palladium⁽⁰⁾; In tetrahydrofuran; N2-atmosphere; stoich. amts., 5% catalyst, in THF/N-methylpyrrolidinone=19:1, 60°C, 4 weeks; solvent removal (reduced pressure), chromy. (SiO2, THF/hexane=10:1, then7:3; then fresh column, CHCl3/hexane=1:1), HPLC (Raining Dynamac Si, CH Cl3/hexane=7:3);