2-[(dimethylamino)methyl]phenylgold(I)

Base Information

• Chemical Name: 2-[(dimethylamino)methyl]phenylgold(I)
• CAS No.: 66539-72-8
• Molecular Formula: C₉H₁₂AuN
• Molecular Weight: 331.167
• Mol file: 66539-72-8.mol

Synonyms:

Chemical Property of 2-[(dimethylamino)methyl]phenylgold(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-[(dimethylamino)methyl]phenylgold(I)

There total 2 articles about 2-[(dimethylamino)methyl]phenylgold(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

bis(2-[(dimethylamino)methyl]phenyl)goldlithium + trimethyltin bromide (1066-44-0) → 2-[(dimethylamino)methyl]phenylgold(I) (66539-72-8) + trimethyl[2-(dimethylamino)methyl]phenyltin (138174-71-7)

Guidance literature:

In benzene; byproducts: LiBr; (N2); soln. of Me3SnBr was added to soln. of AuLi compd.; formed ppt. was filtered off, concd. filtrate yielded tin compd.; ppt. was washed with benzene and ether, giving pure gold complex; elem. anal.;

DOI:10.1016/S0022-328X(00)82423-7

Reference yield:

(triphenylarsine)gold(I) chloride (25749-29-5) + 2-(N,N-dimethylaminomethyl)phenyllithium (56174-66-4) → 2-[(dimethylamino)methyl]phenylgold(I) (66539-72-8)

Guidance literature:

In diethyl ether; byproducts: LiCl; (N2); solid gold complex was added to suspn. of Li compd. at -20°C, mixt. was stirred for 1 h at the same temp. and 1,5 h at room temp.; mixt. was filtered, ppt. was extd. with benzene and ether yielding solid; identified by (1)H-NMR;

DOI:10.1016/S0022-328X(00)82423-7

Reference yield:

2-[(dimethylamino)methyl]phenylgold(I) (66539-72-8) → (2-[(dimethylamino)methyl]phenyl)(triphenylphosphine)gold(I) (54907-53-8)

Guidance literature:

With P(C₆H₅)3;

DOI:10.1016/S0022-328X(00)82423-7

upstream raw materials:

(triphenylarsine)gold(I) chloride

2-(N,N-dimethylaminomethyl)phenyllithium

trimethyltin bromide

Downstream raw materials:

(2-[(dimethylamino)methyl]phenyl)(triphenylphosphine)gold(I)