10,10-dimethyl-7-thiatricyclo[6.3.0.0[2,6]]undeca-1⁽⁸⁾,2⁽⁶⁾-dien-5-one

Base Information

Chemical Name:10,10-dimethyl-7-thiatricyclo[6.3.0.0[2,6]]undeca-1⁽⁸⁾,2⁽⁶⁾-dien-5-one
CAS No.:1346672-68-1
Molecular Formula:C₁₂H₁₄OS
Molecular Weight:206.309
Hs Code.:

10,10-dimethyl-7-thiatricyclo[6.3.0.0[2,6]]undeca-1<sup>(8)</sup>,2<sup>(6)</sup>-dien-5-one

Synonyms:

Suppliers and Price of 10,10-dimethyl-7-thiatricyclo[6.3.0.0[2,6]]undeca-1⁽⁸⁾,2⁽⁶⁾-dien-5-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Alichem
6,6-Dimethyl-1,2,6,7-tetrahydrodicyclopenta[b,d]thiophen-3(5h)-one
1g
$ 1176.12

Alichem
6,6-Dimethyl-1,2,6,7-tetrahydrodicyclopenta[b,d]thiophen-3(5h)-one
250mg
$ 475.00

Total 2 raw suppliers

Chemical Property of 10,10-dimethyl-7-thiatricyclo[6.3.0.0[2,6]]undeca-1⁽⁸⁾,2⁽⁶⁾-dien-5-one

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

6,6-Dimethyl-1,2,6,7-tetrahydrodicyclopenta[b,d]thiophen-3(5h)-one ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 10,10-dimethyl-7-thiatricyclo[6.3.0.0[2,6]]undeca-1⁽⁸⁾,2⁽⁶⁾-dien-5-one

There total 10 articles about 10,10-dimethyl-7-thiatricyclo[6.3.0.0[2,6]]undeca-1⁽⁸⁾,2⁽⁶⁾-dien-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.56%

: 1346672-67-0
3-chloro-1-(5,5-dimethyl-5,6-dihydro-4H-cyclopenta[b]thiophen-2-yl)propan-1-one

: 1346672-68-1
10,10-dimethyl-7-thiatricyclo[6.3.0.0[2,6]]undeca-1⁽⁸⁾,2⁽⁶⁾-dien-5-one

Guidance literature:: With sulfuric acid; at 90 ℃;

Reference yield:

: 20500-49-6
3,3-dimethylcyclopentanone

: 1346672-68-1
10,10-dimethyl-7-thiatricyclo[6.3.0.0[2,6]]undeca-1⁽⁸⁾,2⁽⁶⁾-dien-5-one

Guidance literature:: Multi-step reaction with 7 steps

1.1: trichlorophosphate / dichloromethane / 1.5 h / 0 - 20 °C / Inert atmosphere

1.2: 19 h / Reflux

1.3: 0.75 h / Cooling with ice

2.1: triethylamine / dichloromethane / 6 h / Inert atmosphere; Reflux

3.1: water; lithium hydroxide / ethanol; tetrahydrofuran / 4 h / 60 °C

3.2: 20 °C / pH 1.5

4.1: thionyl chloride / N,N-dimethyl-formamide / toluene / 1 h / Reflux

5.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 18 h / 0 - 20 °C / Inert atmosphere

6.1: tetrahydrofuran / 2.5 h / -70 - 0 °C / Inert atmosphere

6.2: -70 - -10 °C

7.1: sulfuric acid / 90 °C

With thionyl chloride; sulfuric acid; water; triethylamine; N-ethyl-N,N-diisopropylamine; lithium hydroxide; trichlorophosphate; N,N-dimethyl-formamide; In tetrahydrofuran; ethanol; dichloromethane; toluene;

Reference yield:

: 2758-18-1
3-Methyl-2-cyclopenten-1-one

: 1346672-68-1
10,10-dimethyl-7-thiatricyclo[6.3.0.0[2,6]]undeca-1⁽⁸⁾,2⁽⁶⁾-dien-5-one

Guidance literature:: Multi-step reaction with 8 steps

1.1: copper(l) iodide / diethyl ether / 3.5 h / 0 °C / Inert atmosphere

1.2: 3.5 h / 0 °C

1.3: 0.5 h

2.1: trichlorophosphate / dichloromethane / 1.5 h / 0 - 20 °C / Inert atmosphere

2.2: 19 h / Reflux

2.3: 0.75 h / Cooling with ice

3.1: triethylamine / dichloromethane / 6 h / Inert atmosphere; Reflux

4.1: water; lithium hydroxide / ethanol; tetrahydrofuran / 4 h / 60 °C

4.2: 20 °C / pH 1.5

5.1: thionyl chloride / N,N-dimethyl-formamide / toluene / 1 h / Reflux

6.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 18 h / 0 - 20 °C / Inert atmosphere

7.1: tetrahydrofuran / 2.5 h / -70 - 0 °C / Inert atmosphere

7.2: -70 - -10 °C

8.1: sulfuric acid / 90 °C

With copper(l) iodide; thionyl chloride; sulfuric acid; water; triethylamine; N-ethyl-N,N-diisopropylamine; lithium hydroxide; trichlorophosphate; N,N-dimethyl-formamide; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; toluene;