NdI(5,10,15,20-tetraphenylporphyrinate)(1,2-dimethoxyethane)

Base Information

Chemical Name:NdI(5,10,15,20-tetraphenylporphyrinate)(1,2-dimethoxyethane)
CAS No.:479064-07-8
Molecular Formula:C₄₈H₃₈IN₄NdO₂
Molecular Weight:974
Hs Code.:

Synonyms:

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Chemical Property of NdI(5,10,15,20-tetraphenylporphyrinate)(1,2-dimethoxyethane)

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Technology Process of NdI(5,10,15,20-tetraphenylporphyrinate)(1,2-dimethoxyethane)

There total 1 articles about NdI(5,10,15,20-tetraphenylporphyrinate)(1,2-dimethoxyethane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 229182-84-7,1000788-84-0
NdI₃(THF)4

: Li₂(5,10,15,20-tetraphenylporphyrinate)(1,2-dimethoxyethane)

: 479064-07-8
NdI(5,10,15,20-tetraphenylporphyrinate)(1,2-dimethoxyethane)

Guidance literature:: In toluene; under N2; soln. of NdI3(THF)4 and Li2TPP(DME) in toluene heated under reflux for 4 h; hot soln. filtered, residue extracted with CHCl3, extract filtered and combined with toluene filtrate, concd., layered with pentane, ppt. filtered off; elem. anal.;
DOI:10.1021/ic034217g

Reference yield: 64.0%

: 479064-07-8
NdI(5,10,15,20-tetraphenylporphyrinate)(1,2-dimethoxyethane)

: potassium tris(1-pyrazolyl)borate

: Nd(5,10,15,20-tetraphenylporphyrinate)(hydridotris(1-pyrazolyl)borate)

Guidance literature:: In 1,2-dimethoxyethane; under N2; borate added to soln. of Nd complex in DME under stirring, stirred at room temp. for 12 h; evapd. in vacuo, residue extd. with CH2Cl2, extract filtered, filtrate layered with pentane, crystd. on cooling at -10°C for 12 h, crystals sepd., further crop of crystals from mother liquor after concn. and cooling; elem. anal.;
DOI:10.1021/ic034217g

Reference yield: 30.0%

: potassium (cyclopentadienyl)tris(diethylphosphinito)cobaltate(I)

: 479064-07-8
NdI(5,10,15,20-tetraphenylporphyrinate)(1,2-dimethoxyethane)

: Nd(5,10,15,20-tetraphenylporphyrinate)((cyclopentadienyl)tris(diethylphosphinito)cobaltate(I))

Guidance literature:: In tetrahydrofuran; under N2; K(CpCo(PO(OEt)2)3) added to soln. of Nd complex in THF, stirred at room temp. for 12 h; solvent removed in vacuo, residue extd. with toluene, filtered, concd., layered with pentane, cooled to -78°C for 24 h, ppt. sepd. and recrystd. from CH2Cl2/pentane, crystals washed with pentane; elem. anal.;
DOI:10.1021/ic034217g