tetra(mesityl)oxalamidine(triphenylphosphine)copper(I) tetrafluoroborate

Base Information

• Chemical Name: tetra(mesityl)oxalamidine(triphenylphosphine)copper(I) tetrafluoroborate
• CAS No.: 723312-48-9
• Molecular Formula: BF₄*C₅₆H₆₁CuN₄P
• Molecular Weight: 971.452
• Mol file: 723312-48-9.mol

Synonyms:

Chemical Property of tetra(mesityl)oxalamidine(triphenylphosphine)copper(I) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of tetra(mesityl)oxalamidine(triphenylphosphine)copper(I) tetrafluoroborate

There total 1 articles about tetra(mesityl)oxalamidine(triphenylphosphine)copper(I) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + tetra(mesityl)oxalic amidine (286476-84-4) + triphenylphosphine (603-35-0) → tetra(mesityl)oxalamidine(triphenylphosphine)copper(I) tetrafluoroborate (723312-48-9)

Guidance literature:

In toluene; all manipulations under Ar; suspn. of Cu complex and oxalamidine in toluene stirred for 20 min, soln. of PPh3 in toluene added dropwise, heated under reflux for 4 h; concd., n-hexane added dropwise until crystn. started, stored at -25°C for 12 h, ppt. filtered off, washed with n-hexane, dried under vac.; elem. anal.;

DOI:10.1002/zaac.200300181

Reference yield:

tetra(mesityl)oxalamidine(triphenylphosphine)copper(I) tetrafluoroborate (723312-48-9) + toluene (108-88-3,15644-74-3,16713-13-6) → tetra(mesityl)oxalamidine(triphenylphosphine)copper(I) tetrafluoroborate * 2(toluene)

Guidance literature:

In toluene; recrystn. of the complex from toluene;

DOI:10.1002/zaac.200300181

upstream raw materials:

tetra(mesityl)oxalic amidine

triphenylphosphine