(Et₄N) chromium pentacarbonyl phenyl thiocarbonate

Base Information

• Chemical Name: (Et₄N) chromium pentacarbonyl phenyl thiocarbonate
• CAS No.: 121918-83-0
• Molecular Formula: C₈H₂₀N*C₁₂H₅CrO₇S
• Molecular Weight: 475.483
• Mol file: 121918-83-0.mol

Synonyms:

Chemical Property of (Et₄N) chromium pentacarbonyl phenyl thiocarbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Et₄N) chromium pentacarbonyl phenyl thiocarbonate

There total 3 articles about (Et₄N) chromium pentacarbonyl phenyl thiocarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chromium(0) hexacarbonyl (199620-14-9,13007-92-6) → (Et4N) chromium pentacarbonyl phenyl thiocarbonate (121918-83-0)

Guidance literature:

Multi-step reaction with 3 steps

1: neat (no solvent)

2: tetrahydrofuran

3: tetrahydrofuran

In tetrahydrofuran;

DOI:10.1021/ja00200a031

Reference yield:

pentacarbonyl(tetrahydrofuran)chromium(0) (15038-41-2) → (Et4N) chromium pentacarbonyl phenyl thiocarbonate (121918-83-0)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: tetrahydrofuran

In tetrahydrofuran;

DOI:10.1021/ja00200a031

Reference yield:

{(C2H5)4N}(1+)*{Cr(CO)5OC6H5}(1-)={(C2H5)4N}{Cr(CO)5OC6H5} (121918-63-6) + carbon oxide sulfide (463-58-1) → (Et4N) chromium pentacarbonyl phenyl thiocarbonate (121918-83-0)

Guidance literature:

In tetrahydrofuran; in a Schlenk flask, at 0°C, 1 atm COS; addn. of hexane (pptn.), filtration, recrystn. from acetone/ether/hexane;

DOI:10.1021/ja00200a031

upstream raw materials:

{(C₂H₅)4N}⁽¹⁺⁾*{Cr(CO)5OC₆H₅}^(1-)={(C₂H₅)4N}{Cr(CO)5OC₆H₅}

carbon oxide sulfide

chromium⁽⁰⁾ hexacarbonyl

pentacarbonyl(tetrahydrofuran)chromium⁽⁰⁾