[(Nb(MeCN)(CH2SiMe3)3)2(μ-1,3-NC6H4N)]

Base Information

Chemical Name:[(Nb(MeCN)(CH2SiMe3)3)2(μ-1,3-NC6H4N)]
CAS No.:574742-09-9
Molecular Formula:C₃₄H₇₆N₄Nb₂Si₆
Molecular Weight:895.33
Hs Code.:

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Chemical Property of [(Nb(MeCN)(CH2SiMe3)3)2(μ-1,3-NC6H4N)]

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Technology Process of [(Nb(MeCN)(CH2SiMe3)3)2(μ-1,3-NC6H4N)]

There total 1 articles about [(Nb(MeCN)(CH2SiMe3)3)2(μ-1,3-NC6H4N)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 299188-36-6
[(Nb(acetonitrile)2Cl3)2(μ-1,3-NC6H4N)]

: 13170-43-9
(trimethylsilyl)methylmagnesium chloride

: 574742-09-9
[(Nb(CH3CN)(CH2SiMe3)3)2(μ-1,3-NC6H4N)]

Guidance literature:: In diethyl ether; under Ar atm. to suspn. Nb complex in Et2O at -78°C soln. Grignard was added dropwise and stirred overnight at room temp.; soln. was filtered, residue was extracted with Et2O, solvent was removedin vacuo; elem. anal.;
DOI:10.1039/b211126h

Reference yield: 73.0%

: 574742-09-9
[(Nb(MeCN)(CH2SiMe3)3)2(μ-1,3-NC6H4N)]

: 119072-54-7,2769-71-3
2,6-dimethylphenyl isonitrile

: 697310-70-6
[(Nb(η2-Me3SiCH2C=NC6H3Me2-2,6)2(CH2SiMe3))2(μ-1,3-NC6H4N)]

Guidance literature:: In hexane; under N2; hexane soln. of isocyanide (4 equiv.) added dropwise to Nb complex in hexane at room temp.; stirred for 20 min; filtered; solvent removed from filtrate in vac.; elem. anal.;
DOI:10.1016/j.jorganchem.2004.01.029