Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2

Base Information

• Chemical Name: Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2
• CAS No.: 897400-50-9
• Molecular Formula: C₂₅H₃₁ClNiOP₂
• Molecular Weight: 503.611
• Mol file: 897400-50-9.mol

Synonyms:

Chemical Property of Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2

There total 1 articles about Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + 2-chloropropiophenone (6323-18-8) + Dimethyl(phenyl)phosphine (672-66-2) → Ni(C6H4-o-C(O)CH2CH3)(Cl)(PMe2Ph)2 (897400-50-9)

Guidance literature:

In toluene; under N2 atm. PMe2Ph was added to suspn. Ni(cod)2 in toluene at -78°C, allowed to warm to room temp., 2-chloropropiophenone was added andstirred at 45°C for 4 h; solvent was evapd. in vacuo, residue was extd. with THF, cooled to -20°C; elem. anal.;

DOI:10.1021/om060183j

Reference yield: 42.0%

Ni(C6H4-o-C(O)CH2CH3)(Cl)(PMe2Ph)2 (897400-50-9) → Ni(P(CH3)2C6H5)2(C6H4COCHCH3)

Guidance literature:

With potassium tert-butoxide; In tetrahydrofuran; under N2 atm. soln. t-BuOK in THF was added at -78°C to soln. Ni complex in THF, allowed to warm to room temp.; solvent was removed in vacuo, residue was extd. with THF, concd. and cooled to -20°C; elem. anal.;

DOI:10.1021/om060183j

upstream raw materials:

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

2-chloropropiophenone

Dimethyl(phenyl)phosphine

Refernces