Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2

Base Information

Chemical Name:Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2
CAS No.:897400-50-9
Molecular Formula:C₂₅H₃₁ClNiOP₂
Molecular Weight:503.611
Hs Code.:

Ni(C<sub>6</sub>H<sub>4</sub>-o-C(O)CH<sub>2</sub>CH<sub>3</sub>)(Cl)(PMe<sub>2</sub>Ph)2

Synonyms:

Suppliers and Price of Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2

There total 1 articles about Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 1295-35-8
bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

: 6323-18-8
2-chloropropiophenone

: 672-66-2
Dimethyl(phenyl)phosphine

: 897400-50-9
Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2

Guidance literature:: In toluene; under N2 atm. PMe2Ph was added to suspn. Ni(cod)2 in toluene at -78°C, allowed to warm to room temp., 2-chloropropiophenone was added andstirred at 45°C for 4 h; solvent was evapd. in vacuo, residue was extd. with THF, cooled to -20°C; elem. anal.;
DOI:10.1021/om060183j

Reference yield: 42.0%

: 897400-50-9
Ni(C₆H₄-o-C(O)CH₂CH₃)(Cl)(PMe₂Ph)2

: Ni(P(CH₃)2C₆H₅)2(C₆H₄COCHCH₃)

Guidance literature:: With potassium tert-butoxide; In tetrahydrofuran; under N2 atm. soln. t-BuOK in THF was added at -78°C to soln. Ni complex in THF, allowed to warm to room temp.; solvent was removed in vacuo, residue was extd. with THF, concd. and cooled to -20°C; elem. anal.;
DOI:10.1021/om060183j