tris(cyclohexylisocyanide)bis(triphenylphosphine)cobalt(I) perchlorate

Base Information

• Chemical Name: tris(cyclohexylisocyanide)bis(triphenylphosphine)cobalt(I) perchlorate
• CAS No.: 169233-60-7
• Molecular Formula: C₅₇H₆₃CoN₃P₂*ClO₄
• Molecular Weight: 1010.54

Synonyms:

Chemical Property of tris(cyclohexylisocyanide)bis(triphenylphosphine)cobalt(I) perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tris(cyclohexylisocyanide)bis(triphenylphosphine)cobalt(I) perchlorate

There total 2 articles about tris(cyclohexylisocyanide)bis(triphenylphosphine)cobalt(I) perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

Co(CNC6H11)4(As(C6H5)3)2(2+)*2ClO4(1-)=[Co(CNC6H11)4(As(C6H5)3)2](ClO4)2 + triphenylphosphine (603-35-0) → tris(cyclohexylisocyanide)bis(triphenylphosphine)cobalt(II) perchlorate + tris(cyclohexylisocyanide)bis(triphenylphosphine)cobalt(I) perchlorate (169233-60-7)

Guidance literature:

In dichloromethane; dissolving of Co-complex, cooling (ice), dropwise addn. of ligand soln. (stirring); pptn. on dropwise ether addn., cooling in ice (45 min), filtration, washing (ether), dissolving in CH2Cl2, filtration, pptn. by dropwise addn. of ether, cooling in ice, filtration, washing (ether); elem. anal.;

DOI:10.1080/00945719708003157

Reference yield: 51.0%

Co(CNC6H11)4(As(C6H5)3)2(2+)*2ClO4(1-)=[Co(CNC6H11)4(As(C6H5)3)2](ClO4)2 + triphenylphosphine (603-35-0) → tris(cyclohexylisocyanide)bis(triphenylphosphine)cobalt(I) perchlorate (169233-60-7)

Guidance literature:

With N₂H₄*H₂O; In dichloromethane; dissolving of Co-complex, cooling (ice), dropwise addn. of ligand soln. (stirring), pptn. on ether addn., cooling in ice (1.5 h), filtration, washing (ether), dissolving in CH2Cl2, addn. of reagent (3 drops), stirring (1.5 min); decantation, filtration, pptn. on dropwise addn. of ether, cooling in ice (30 min), filtration, washing (ether); elem. anal.;

DOI:10.1080/00945719708003157

Reference yield: 64.0%

tris(cyclohexylisocyanide)bis(triphenylphosphine)cobalt(I) perchlorate (169233-60-7) + silver perchlorate → tris(cyclohexylisocyanide)bis(triphenylphosphine)cobalt(II) perchlorate

Guidance literature:

In dichloromethane; byproducts: Ag; dissolving of Co-complex, filtration, addn. of Ag-salt, vigorous stirring (5.0 min); decantation, filtration, pptn. on ether addn., cooling in ice (45 min), filtration, washing (ether), dissolving in CH2Cl2, filtration, pptn. on dropwise addn. of ether, cooling in ice (45 min), filtration, washing (ether); elem. anal.;

DOI:10.1080/00945719708003157

upstream raw materials:

triphenylphosphine

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 169233-60-7 tris(cyclohexylisocyanide)bis(triphenylphosphine)cobalt(I) perchlorate

Send

Send

Metric Ton KG G Pound L ML

Send

Send