Technology Process of C19H32O3
There total 4 articles about C19H32O3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium / decane; dichloromethane / 0 - 20 °C
2.1: copper(l) cyanide / tetrahydrofuran; diethyl ether / 3.5 h / -55 - -10 °C
3.1: 2,6-dimethylpyridine / dichloromethane / 1.5 h / -78 °C
4.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 3 h / -78 °C
4.2: 3 h / -78 °C
5.1: trifluoroacetic acid / dichloromethane / 1.83 h / -20 - 0 °C
With
2,6-dimethylpyridine; tert.-butylhydroperoxide; oxalyl dichloride; bis(acetylacetonate)oxovanadium; copper(l) cyanide; dimethyl sulfoxide; trifluoroacetic acid;
In
tetrahydrofuran; diethyl ether; decane; dichloromethane;
4.1: Swern oxidation / 4.2: Swern oxidation;
DOI:10.1002/chem.201102630
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: copper(l) cyanide / tetrahydrofuran; diethyl ether / 3.5 h / -55 - -10 °C
2.1: 2,6-dimethylpyridine / dichloromethane / 1.5 h / -78 °C
3.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 3 h / -78 °C
3.2: 3 h / -78 °C
4.1: trifluoroacetic acid / dichloromethane / 1.83 h / -20 - 0 °C
With
2,6-dimethylpyridine; oxalyl dichloride; copper(l) cyanide; dimethyl sulfoxide; trifluoroacetic acid;
In
tetrahydrofuran; diethyl ether; dichloromethane;
3.1: Swern oxidation / 3.2: Swern oxidation;
DOI:10.1002/chem.201102630
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 2,6-dimethylpyridine / dichloromethane / 1.5 h / -78 °C
2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 3 h / -78 °C
2.2: 3 h / -78 °C
3.1: trifluoroacetic acid / dichloromethane / 1.83 h / -20 - 0 °C
With
2,6-dimethylpyridine; oxalyl dichloride; dimethyl sulfoxide; trifluoroacetic acid;
In
dichloromethane;
2.1: Swern oxidation / 2.2: Swern oxidation;
DOI:10.1002/chem.201102630