(thiophene-2-(N,N-bis(diphenylphosphino)methylamine))(η6-p-cymene)chloridoruthenium(II) chloride

Base Information

• Chemical Name: (thiophene-2-(N,N-bis(diphenylphosphino)methylamine))(η6-p-cymene)chloridoruthenium(II) chloride
• CAS No.: 1277180-93-4
• Molecular Formula: C₃₉H₃₉ClNP₂RuS*Cl
• Molecular Weight: 787.735
• Mol file: 1277180-93-4.mol

Synonyms:

Chemical Property of (thiophene-2-(N,N-bis(diphenylphosphino)methylamine))(η6-p-cymene)chloridoruthenium(II) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (thiophene-2-(N,N-bis(diphenylphosphino)methylamine))(η6-p-cymene)chloridoruthenium(II) chloride

There total 3 articles about (thiophene-2-(N,N-bis(diphenylphosphino)methylamine))(η6-p-cymene)chloridoruthenium(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + thiophene-2-(N,N-bis(diphenylphosphino)methylamine) (1215198-72-3) → [Ru((PPh2)2NCH2-C4H3S)(η6-p-cymene)Cl]Cl (1277180-93-4)

Guidance literature:

In tetrahydrofuran; (Ar); using Schlenk techniques; addn. of soln. of (Ph2P)2NCH2C4H3S (1 equiv.) in THF to soln. of (Ru(p-cymene)Cl2)2 (1 equiv.) in THF, stirring at room temp. for 1 h; filtration, evapn. under vac., washing with Et2O, drying under vac., recrystn. from Et2O/CH2Cl2; elem. anal.;

DOI:10.1016/j.poly.2010.12.011

Reference yield: 92.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + thiophene-2-(N,N-bis(diphenylphosphino)methylamine) (1215198-72-3) → (thiophene-2-(N,N-bis(diphenylphosphino)methylamine))(η6-p-cymene)chloridoruthenium(II) chloride (1277180-93-4)

Guidance literature:

In tetrahydrofuran; (Ar), soln. of Ru complex in THF treated with soln. of 1 equiv. of ligand in THF, stirred at room temp. for 1 h; filtered, evapd.(vac.), washed (Et2O), dried (vac.), recrystd.(Et2O/CH2Cl2), elem. anal.;

DOI:10.1016/j.ica.2010.12.028

Reference yield:

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + thiophene-2-(N,N-bis(diphenylphosphino)methylamine) (1215198-72-3) → [Ru((PPh2)2NCH2-C4H3S)(η6-p-cymene)Cl]Cl (1277180-93-4) + trans-[bis(thiophene-2-(N,N-bis(diphenylphosphino)methylamine))dichloridoruthenium(II)]

Guidance literature:

In not given; (Ar); using Schlenk techniques; treatment of (Ph2P)2NCH2C4H3S (1 equiv.)with (Ru(p-cymene)Cl2)2 (0.5 equiv.); monitoring by NMR;

DOI:10.1016/j.poly.2010.12.011

upstream raw materials:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

thiophene-2-(N,N-bis(diphenylphosphino)methylamine)