arachno-B₉H₁₃(PPh₃)2

Base Information

Chemical Name:arachno-B₉H₁₃(PPh₃)2
CAS No.:389070-33-1
Molecular Formula:C₃₆H₄₁B₉P₂
Molecular Weight:632.968
Hs Code.:

arachno-B<sub>9</sub>H<sub>13</sub>(PPh<sub>3</sub>)2

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of arachno-B₉H₁₃(PPh₃)2

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Technology Process of arachno-B₉H₁₃(PPh₃)2

There total 1 articles about arachno-B₉H₁₃(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

: 19624-22-7
pentaborane⁽⁹⁾

: 603-35-0
triphenylphosphine

: B₉H₁₄^(1-)

: 389070-33-1
arachno-B₉H₁₃(PPh₃)2

: triphenylphosphine borane

Guidance literature:: With (C₅H₅)2ZrCl₂; n-BuLi; In tetrahydrofuran; hexane; dichloromethane; THF condensed to Cp2ZrCl2 at -196°C, nBuLi/hexane added dropwise (-78°C, under N2), stirred (-78°C, 1h), degassed at -196°C, B5H9 introduced, warmed to room temp. over 1h, volatiles evapd.at room temp., PPh3 in CH2Cl2 added; air introduced into soln. under stirring at 0°C for 1 h, solvent was evapd., column chromy. with CH2Cl2/hexane, recrystd. from CH2Cl2/ether; elem. anal.;
DOI:10.1021/ic010810r