(o-tert-butylphenyl)3GeBr

Base Information

Chemical Name:(o-tert-butylphenyl)3GeBr
CAS No.:1322732-27-3
Molecular Formula:C₃₀H₃₉BrGe
Molecular Weight:552.134
Hs Code.:

Synonyms:

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Chemical Property of (o-tert-butylphenyl)3GeBr

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Technology Process of (o-tert-butylphenyl)3GeBr

There total 1 articles about (o-tert-butylphenyl)3GeBr which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 13450-92-5
germanium tetrabromide

: 7073-99-6
2-tert-butylbromobenzene

: 7439-95-4
magnesium

: 1322732-27-3
(o-tert-butylphenyl)3GeBr

Guidance literature:: With I₂; In tetrahydrofuran; Schlenk; THF soln. of ligand (49.76 mmol) added to Mg chips (72.8 mmol),one crystal of I2 added, refluxed for 90 min, cooled to room temp., THF soln. of GeBr4 (16.6 mmol) added, mixt. refluxed under N2 for 60 min; cooled to room temp., poured over aq. HBr (ice bath), extd. (benzene), org. layer dried (MgSO4), evapd., elem. anal.;
DOI:10.1016/j.jorganchem.2011.05.012

Reference yield: 93.0%

: 16853-85-3
lithium aluminium tetrahydride

: 1322732-27-3
(o-tert-butylphenyl)3GeBr

: 1322732-30-8
(o-tert-butylphenyl)3GeH

Guidance literature:: In diethyl ether; Schlenk; Et2O soln. of Ge compd. (1.81 mmol) treated with Et2O suspn. ofLiAlH4 (6.1 mmol) at 0°C, mixt. stirred at room temp. for 3 h; quenched (H2O), org. layer dried (MgSO4), evapd., elem. anal.;
DOI:10.1016/j.jorganchem.2011.05.012

Reference yield: 69.0%

: 1322732-27-3
(o-tert-butylphenyl)3GeBr

: potassium hydroxide

: 1322732-34-2
(o-tert-butylphenyl)3GeOH

Guidance literature:: In ethanol; N2; EtOH soln. of Ge compd. (1.41 mmol) treated with EtOH soln. of KOH (2.23 mmol), mixt. refluxed under N2 for 24 h; evapd., treated (benzene), filtered (Celite), evapd., elem. anal.;
DOI:10.1016/j.jorganchem.2011.05.012