dicarbonylchloro(2-phenylazobenzene-N')rhodium(I)

Base Information

• Chemical Name: dicarbonylchloro(2-phenylazobenzene-N')rhodium(I)
• CAS No.: 62448-07-1
• Molecular Formula: C₁₄H₁₀ClN₂O₂Rh
• Molecular Weight: 376.604
• Mol file: 62448-07-1.mol

Synonyms:

Chemical Property of dicarbonylchloro(2-phenylazobenzene-N')rhodium(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dicarbonylchloro(2-phenylazobenzene-N')rhodium(I)

There total 1 articles about dicarbonylchloro(2-phenylazobenzene-N')rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

rhodium(III) chloride trihydrate + Azobenzene (1227476-15-4) → dicarbonylchloro(2-phenylazobenzene-N')rhodium(I) (205327-95-3,62448-07-1)

Guidance literature:

In N,N-dimethyl-formamide; RhCl3*3H2O in DMF stirred with azobenzene in N2 atm. for 0.5 h; refluxedunder N2 atm. for 2 h in oil bath; cooled to room temp.; water added; react. mixt. kept at 5°C for 1 h, filtered in N2 atm.; washed with water and acetone; dried in vac.; elem. anal.;

DOI:10.1080/15533174.2010.522539

Reference yield: 97.0%

dicarbonylchloro(2-phenylazobenzene-N')rhodium(I) (205327-95-3,62448-07-1) → dicarbonyl (2-phenylazophenyl-C'N')rhodium(I) (39043-25-9)

Guidance literature:

In N,N-dimethyl-formamide; Rh complex in DMF stirred under Ar atm. for 8 h; DMF vac. evapd.; recrystd. from DMF-MeOH; elem. anal.;

DOI:10.1080/15533174.2010.522539

upstream raw materials:

Azobenzene

Downstream raw materials:

dicarbonyl (2-phenylazophenyl-C'N')rhodium(I)