(CO)5W(P(C₆H₅)2F)

Base Information

Chemical Name:(CO)5W(P(C₆H₅)2F)
CAS No.:102982-83-2
Molecular Formula:C₁₇H₁₀FO₅PW
Molecular Weight:528.086
Hs Code.:

Synonyms:

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Chemical Property of (CO)5W(P(C₆H₅)2F)

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Technology Process of (CO)5W(P(C₆H₅)2F)

There total 8 articles about (CO)5W(P(C₆H₅)2F) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: ((C₆H₅)3P)2N⁽¹⁺⁾*(C₆H₅)2P(W(CO)5)2^(1-) = {(C₆H₅)2P(W(CO)5)2}{((C₆H₅)3P)2N}

: 102982-83-2
(CO)5W(P(C₆H₅)2F)

Guidance literature:: With I₂; NaF; In dichloromethane; acetonitrile; byproducts: {(PPh3)2N}{W(CO)5I}; the phosphane-complex and I2 were dissolved (CH2Cl2); stirred for 2 h (20°C); CH2Cl2 was removed in vacuo; extraktion (toluene); residue contains (W(CO)5I)(PNP); filtrate was evaporated; residue was treated with CH3CN; refluxed with NaF for 10 h; solvent was removed; DC-chromatography (Kieselgel, CH2Cl2/petroleum ether 40/60); elem. anal., IR, NMR;

Reference yield:

: 18399-62-7
W(CO)5(PPh2H)

: 102982-83-2
(CO)5W(P(C₆H₅)2F)

Guidance literature:: Multi-step reaction with 5 steps

1: n-BuLi / methanol; diethyl ether

2: benzene

3: acetonitrile

4: hexane; diethyl ether

5: not given

With n-BuLi; In methanol; diethyl ether; hexane; acetonitrile; benzene;
DOI:10.1021/om970418e

Reference yield:

: 14586-49-3
(pyridine)pentacarbonyltungsten⁽⁰⁾

: 18399-62-7
W(CO)5(PPh2H)

: 102982-83-2
(CO)5W(P(C₆H₅)2F)

Guidance literature:: Multi-step reaction with 2 steps

1: diethyl ether; methanol

2: I₂; NaF / acetonitrile; dichloromethane

With I₂; NaF; In methanol; diethyl ether; dichloromethane; acetonitrile;