Trimethyl 5-nitrobenzene-1,2,3-tricarboxylate

Base Information

Chemical Name:Trimethyl 5-nitrobenzene-1,2,3-tricarboxylate
CAS No.:16134-19-3
Molecular Formula:C₁₂H₁₁NO₈
Molecular Weight:297.221
Hs Code.:
DSSTox Substance ID:DTXSID401334551

Synonyms:16134-19-3;DTXSID401334551;Trimethyl 5-nitro-1,2,3-benzenetricarboxylate

Suppliers and Price of Trimethyl 5-nitrobenzene-1,2,3-tricarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Trimethyl 5-nitrobenzene-1,2,3-tricarboxylate

Chemical Property:

XLogP3:1.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:6
Exact Mass:297.04846631
Heavy Atom Count:21
Complexity:417

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(=O)C1=CC(=CC(=C1C(=O)OC)C(=O)OC)[N+](=O)[O-]

Technology Process of Trimethyl 5-nitrobenzene-1,2,3-tricarboxylate

There total 8 articles about Trimethyl 5-nitrobenzene-1,2,3-tricarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 55821-21-1,55781-65-2,126188-30-5,53076-44-1
1,2,3,3a,4,5,9,10,10a,10b-decahydropyrene

: 16134-19-3
5-nitro-benzene-1,2,3-tricarboxylic acid trimethyl ester

Guidance literature:: With nitric acid; at 180 ℃; Erwaermen des aus dem Reaktionsprodukt hergestellten Silber-Salzes mit Methyljodid in Benzol;
DOI:10.1039/jr9450000286

Reference yield:

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 16134-19-3
5-nitro-benzene-1,2,3-tricarboxylic acid trimethyl ester

Guidance literature:: With diethyl ether;
DOI:10.1021/jo01269a026 DOI:10.1002/hlca.19490320534

Reference yield:

: 526-73-8
1,2,3-trimethylbenzene

: 16134-19-3
5-nitro-benzene-1,2,3-tricarboxylic acid trimethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 80 percent / NaOH, KMnO₄ / H₂O / 2 h / Heating

2: 88 percent / 1M KOH / propan-2-ol

3: 80 percent / conc. H₂SO₄, KNO₃ / 6 h / 120 °C

4: methanol; diethyl ether

With potassium hydroxide; sodium hydroxide; potassium permanganate; sulfuric acid; potassium nitrate; In methanol; diethyl ether; water; isopropyl alcohol;