discoipyrrole A

Base Information

Chemical Name:discoipyrrole A
CAS No.:1452507-29-7
Molecular Formula:C₂₇H₂₃NO₅
Molecular Weight:441.483
Hs Code.:

Synonyms:

Suppliers and Price of discoipyrrole A

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of discoipyrrole A

Chemical Property:

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Technology Process of discoipyrrole A

There total 5 articles about discoipyrrole A which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₀H₃₁NO₄

: 1452507-29-7
discoipyrrole A

Guidance literature:: Multi-step reaction with 3 steps

1: potassium hydroxide; N-benzyl-N,N,N-triethylammonium chloride / tetrahydrofuran; water; methanol / 16 h / Reflux

2: boron tribromide / dichloromethane / 16 h / -78 - 20 °C / Inert atmosphere

3: oxoperoxymolybdenum(pyridine)(hexamethylphosphoric triamide) / dichloromethane; methanol / 16 h / 20 °C / Inert atmosphere; Darkness

With oxoperoxymolybdenum(pyridine)(hexamethylphosphoric triamide); N-benzyl-N,N,N-triethylammonium chloride; boron tribromide; potassium hydroxide; In tetrahydrofuran; methanol; dichloromethane; water;
DOI:10.1021/acs.orglett.5b03672

Reference yield:

: C₂₉H₂₉NO₄

: 1452507-29-7
discoipyrrole A

Guidance literature:: Multi-step reaction with 2 steps

1: boron tribromide / dichloromethane / 16 h / -78 - 20 °C / Inert atmosphere

2: oxoperoxymolybdenum(pyridine)(hexamethylphosphoric triamide) / dichloromethane; methanol / 16 h / 20 °C / Inert atmosphere; Darkness

With oxoperoxymolybdenum(pyridine)(hexamethylphosphoric triamide); boron tribromide; In methanol; dichloromethane;
DOI:10.1021/acs.orglett.5b03672

Reference yield:

: C₁₃H₉Br₂NO₃

: 1452507-29-7
discoipyrrole A

Guidance literature:: Multi-step reaction with 6 steps

1.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / water; 1,2-dimethoxyethane / 20 h / 85 °C / Inert atmosphere

2.1: potassium tert-butylate / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere

2.2: 1 h / -78 - 0 °C / Inert atmosphere

3.1: palladium 10% on activated carbon; hydrogen / tetrahydrofuran / 16 h / 20 °C

4.1: potassium hydroxide; N-benzyl-N,N,N-triethylammonium chloride / tetrahydrofuran; water; methanol / 16 h / Reflux

5.1: boron tribromide / dichloromethane / 16 h / -78 - 20 °C / Inert atmosphere

6.1: oxoperoxymolybdenum(pyridine)(hexamethylphosphoric triamide) / dichloromethane; methanol / 16 h / 20 °C / Inert atmosphere; Darkness

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; palladium 10% on activated carbon; oxoperoxymolybdenum(pyridine)(hexamethylphosphoric triamide); potassium tert-butylate; N-benzyl-N,N,N-triethylammonium chloride; hydrogen; boron tribromide; sodium carbonate; potassium hydroxide; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; dichloromethane; water; 1.1: |Suzuki-Miyaura Coupling / 2.1: |Wittig Olefination / 2.2: |Wittig Olefination;
DOI:10.1021/acs.orglett.5b03672