Fe(C₅H₆)(CO)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)

Base Information

• Chemical Name: Fe(C₅H₆)(CO)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)
• CAS No.: 86050-41-1
• Molecular Formula: C₃₂H₃₀FeOP₂
• Molecular Weight: 548.384
• Mol file: 86050-41-1.mol

Synonyms:

Chemical Property of Fe(C₅H₆)(CO)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Fe(C₅H₆)(CO)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)

There total 3 articles about Fe(C₅H₆)(CO)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

Fe(C5H5)(CO)(P(C6H5)2CH2CH2P(C6H5)2)H + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → Fe(C5H6)(CO)(P(C6H5)2CH2CH2P(C6H5)2) (86050-41-1)

Guidance literature:

In toluene; a soln. of Fe-complex in toluene was saturated with dppe at 20°Cunder N2, reactants were heated (80°C) in absence of light (8 h); solvent was removed under reduced pressure, extd. with light petroleum,concd., chromd. (toluene-light petroleum), evapd., dissolved in acetone, filtered, concd., cooled (-30°C), filtrate was evapd. to dryness, recrystd. from Et2O; elem. anal.; Kinetics;

Reference yield:

lithium aluminium tetrahydride (16853-85-3) + (1,2-bis(diphenylphosphino)ethane)carbonyl(η5-cyclopentadienyl)iron(1+) hexafluorophosphate → Fe(C5H6)(CO)(P(C6H5)2CH2CH2P(C6H5)2) (86050-41-1) + {(η5-C5H5)(Me)(C6H5)2P(CH2)2P(C6H5)2}Fe (51509-19-4)

Guidance literature:

With water; In tetrahydrofuran; a suspn. of Fe-complex in THF was heated under reflux, LiAlH4 was added, stirred under reflux for 15 min, cooled (0°C) and hydrolysed under N2; solvent was removed under reduced pressure, extd. with Et2O, solvent was removed;

Reference yield:

Fe(C5H5)(CO)(P(C6H5)2CH2CH2P(C6H5)2)H → Fe(C5H6)(CO)(P(C6H5)2CH2CH2P(C6H5)2) (86050-41-1) + {(η5-C5H5)(hydrido)(C6H5)2P(CH2)2P(C6H5)2}Fe (51509-20-7)

Guidance literature:

With C₂H₄(P(C₆H₅)2)2; In toluene; thermolysis of educt in toluene at 90°C for 20 h in presence of excess diphos;

DOI:10.1016/S0022-328X(00)98661-3

upstream raw materials:

lithium aluminium tetrahydride

1,2-bis-(diphenylphosphino)ethane