alpha-Methylene-beta-[2-thioxo-1-(trimethylsilyl)ethenyl]benzenepropanenitrile

Base Information

Chemical Name:alpha-Methylene-beta-[2-thioxo-1-(trimethylsilyl)ethenyl]benzenepropanenitrile
CAS No.:86318-63-0
Molecular Formula:C₁₅H₁₇NSSi
Molecular Weight:271.458
Hs Code.:
DSSTox Substance ID:DTXSID501151130

Synonyms:DTXSID501151130;alpha-Methylene-beta-[2-thioxo-1-(trimethylsilyl)ethenyl]benzenepropanenitrile;86318-63-0

Suppliers and Price of alpha-Methylene-beta-[2-thioxo-1-(trimethylsilyl)ethenyl]benzenepropanenitrile

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of alpha-Methylene-beta-[2-thioxo-1-(trimethylsilyl)ethenyl]benzenepropanenitrile

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:271.08509725
Heavy Atom Count:18
Complexity:412

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C[Si](C)(C)C(=C=S)C(C1=CC=CC=C1)C(=C)C#N

Technology Process of alpha-Methylene-beta-[2-thioxo-1-(trimethylsilyl)ethenyl]benzenepropanenitrile

There total 3 articles about alpha-Methylene-beta-[2-thioxo-1-(trimethylsilyl)ethenyl]benzenepropanenitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 86318-46-9
α-(Trimethylsilylethinylthiomethyl)zimtsaeurenitril

: 86318-63-0
2-Methylen-3-phenyl-5-thioxo-4-(trimethylsilyl)-4-pentennitril

Guidance literature:: at 60 ℃; under 0.001 Torr;

Reference yield:

: 1066-54-2
trimethylsilylacetylene

: 86318-63-0
2-Methylen-3-phenyl-5-thioxo-4-(trimethylsilyl)-4-pentennitril

Guidance literature:: Multi-step reaction with 3 steps

1: 1) BuLi, 2) S / 1) ether, hexane, -70 deg C, 30 min, 2) ether, hexane, 2 h, -70 deg C; 2 h, to 0 deg C

2: diethyl ether; hexane / 0.25 h / -70 deg C to 0 deg C

3: 20 percent / 60 °C / 0 Torr

With n-butyllithium; In diethyl ether; hexane;

Reference yield:

: 62785-85-7
LiSCCSiMe₃

: 86318-63-0
2-Methylen-3-phenyl-5-thioxo-4-(trimethylsilyl)-4-pentennitril

Guidance literature:: Multi-step reaction with 2 steps

1: diethyl ether; hexane / 0.25 h / -70 deg C to 0 deg C

2: 20 percent / 60 °C / 0 Torr

In diethyl ether; hexane;