[7-(bis(diphenylamino)phosphino)-1,5,7-triazabicyclo[4.4.0]dec-5-ene]nickel dibromide

Base Information

• Chemical Name: [7-(bis(diphenylamino)phosphino)-1,5,7-triazabicyclo[4.4.0]dec-5-ene]nickel dibromide
• CAS No.: 1065063-74-2
• Molecular Formula: C₃₁H₃₂Br₂N₅NiP
• Molecular Weight: 724.1
• Mol file: 1065063-74-2.mol

Synonyms:

Chemical Property of [7-(bis(diphenylamino)phosphino)-1,5,7-triazabicyclo[4.4.0]dec-5-ene]nickel dibromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [7-(bis(diphenylamino)phosphino)-1,5,7-triazabicyclo[4.4.0]dec-5-ene]nickel dibromide

There total 1 articles about [7-(bis(diphenylamino)phosphino)-1,5,7-triazabicyclo[4.4.0]dec-5-ene]nickel dibromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

nickel(II) bromide dimethoxyethane (28923-39-9) + 7-(bis(diphenylamino)phosphino)-1,5,7-triazabicyclo[4.4.0]dec-5-ene (1065063-52-6) → [7-(bis(diphenylamino)phosphino)-1,5,7-triazabicyclo[4.4.0]dec-5-ene]nickel dibromide (1065063-74-2)

Guidance literature:

In dichloromethane; under N2; mixt. of ligand and Ni complex cooled to -78°C; stirred; CH2Cl2 added dropwise; warmed to room temp. with stirring for 18 h; heated to reflux for 24 h; filtered; ppt. washed with Et2O; dried in vac.; elem. anal.;

DOI:10.1021/om8005933

upstream raw materials:

nickel(II) bromide dimethoxyethane

7-(bis(diphenylamino)phosphino)-1,5,7-triazabicyclo[4.4.0]dec-5-ene