[N-(3-tert-butylsalicylidene)-2,3,4,5,6-pentafluoroanilinato-N'-phenylpyrrolylaldiminato]titanium(IV) dichloride

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Chemical Name:[N-(3-tert-butylsalicylidene)-2,3,4,5,6-pentafluoroanilinato-N'-phenylpyrrolylaldiminato]titanium(IV) dichloride
CAS No.:862374-60-5
Molecular Formula:C₂₈H₂₂Cl₂F₅N₃OTi
Molecular Weight:630.28
Hs Code.:

Synonyms:

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Chemical Property of [N-(3-tert-butylsalicylidene)-2,3,4,5,6-pentafluoroanilinato-N'-phenylpyrrolylaldiminato]titanium(IV) dichloride

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Technology Process of [N-(3-tert-butylsalicylidene)-2,3,4,5,6-pentafluoroanilinato-N'-phenylpyrrolylaldiminato]titanium(IV) dichloride

There total 1 articles about [N-(3-tert-butylsalicylidene)-2,3,4,5,6-pentafluoroanilinato-N'-phenylpyrrolylaldiminato]titanium(IV) dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: K(pyrrole-2-phenylcarbaldimine^(1-))

: 848616-68-2
TiCl₃(3-tBu-2-OC₆H₃CHNC₆F₅)(tetrahydrofuran)

: 862374-60-5
[N-(3-tert-butylsalicylidene)-2,3,4,5,6-pentafluoroanilinato-N'-phenylpyrrolylaldiminato]titanium(IV) dichloride

Guidance literature:: In dichloromethane; byproducts: KCl; (N2); std. Schlenk technique; suspn. of K compd. in CH2Cl2 was slowly added to soln. of Ti complex in CH2Cl2 at -78°C; warmed to room temp.; stirred for 6 h; volatiles removed (vac.); extd. (Et2O); washed (light petroleum); recrystd. (CH2Cl2/light petroleum, -30°C); elem. anal.;
DOI:10.1016/j.jorganchem.2007.04.047

Reference yield:

: 862374-60-5
[N-(3-tert-butylsalicylidene)-2,3,4,5,6-pentafluoroanilinato-N'-phenylpyrrolylaldiminato]titanium(IV) dichloride

: (N-(3-tert-butylsalicylidene)-2,3,4,5,6-pentafluoroanilinato)(N-phenylpyrrolylaldiminato)TiMeCl

Guidance literature:: With tetramethyldialuminoxane; In further solvent(s); (Ar); in toluene-d8/1,2-difluorobenzene; not isolated, detected by NMR;
DOI:10.1021/om0607752

Reference yield:

: 862374-60-5
[N-(3-tert-butylsalicylidene)-2,3,4,5,6-pentafluoroanilinato-N'-phenylpyrrolylaldiminato]titanium(IV) dichloride

: (N-(3-tert-butylsalicylidene)-2,3,4,5,6-pentafluoroanilinato)(N-phenylpyrrolylaldiminato)Ti(⁽¹³⁾C)Cl

Guidance literature:: With ⁽¹³⁾C-methylalumoxane; In further solvent(s); (Ar); in toluene-d8/1,2-difluorobenzene; not isolated, detected by NMR;
DOI:10.1021/om0607752