W(O-2,6-diisopropylphenyl)3Cl₃

Base Information

• Chemical Name: W(O-2,6-diisopropylphenyl)3Cl₃
• CAS No.: 111350-21-1
• Molecular Formula: C₃₆H₅₁Cl₃O₃W
• Molecular Weight: 822.008
• Mol file: 111350-21-1.mol

Synonyms:

Chemical Property of W(O-2,6-diisopropylphenyl)3Cl₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of W(O-2,6-diisopropylphenyl)3Cl₃

There total 2 articles about W(O-2,6-diisopropylphenyl)3Cl₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

2,6-diisopropylphenol (2078-54-8) + tungsten(VI) chloride (13283-01-7) → mer-Cl3W(O(2,6-iPr2C6H3))3 (111350-21-1,116561-00-3)

Guidance literature:

In tetrachloromethane; addn. of soln. of 2,6-(C3H7)2C6H3OH in CCl4 to WCl6 suspended in CCl4 (Ar-atmosphere); stirring under reflux for 5 h;; evapn. and chromy. on silica gel column (toluene/cyclohexane 25/75); crystn. from ethanol at -5°C; elem. anal.;;

Reference yield:

2,6-diisopropylphenol (2078-54-8) + tungsten(VI) chloride (13283-01-7) → W(O-2,6-diisopropylphenyl)3Cl3 (116561-00-3,111350-21-1)

Guidance literature:

In toluene; at 25 ℃;

Reference yield: 81.6%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + mer-Cl3W(O(2,6-iPr2C6H3))3 (111350-21-1,116561-00-3) → Cl2W(ODipp)3(THF) (1607468-34-7)

Guidance literature:

With zinc; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1002/ejic.201301140

upstream raw materials:

2,6-diisopropylphenol

tungsten(VI) chloride

Downstream raw materials:

Cl₂W(ODipp)₃(THF)