C₁₇H₂₂O₈

Base Information

• Chemical Name: C₁₇H₂₂O₈
• CAS No.: 1455231-14-7
• Molecular Formula: C₁₇H₂₂O₈
• Molecular Weight: 354.357
• Mol file: 1455231-14-7.mol

Synonyms:

Chemical Property of C₁₇H₂₂O₈

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₇H₂₂O₈

There total 11 articles about C₁₇H₂₂O₈ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C24H25NO11 → C17H22O8 (1455231-14-7)

Guidance literature:

With sodium methylate; In methanol; at 0 ℃; for 2h;

DOI:10.1016/j.tetlet.2013.07.125

Reference yield:

3-(3',4'-methylenedioxybenzoyl) propanoic acid (41764-07-2) → C17H22O8 (1455231-14-7)

Guidance literature:

Multi-step reaction with 10 steps

1: potassium carbonate / acetone / 3 h

2: N-Bromosuccinimide; ammonium acetate; tetrachloromethane / Reflux

3: triethylamine / dichloromethane / 0.17 h

4: potassium carbonate; (9S,9"S)-9,9"-[phthalazine-1,4-diylbis-(oxy)]bis[10,11-dihydro-6'-methoxycinchonane]; osmium(VIII) oxide; potassium hexacyanoferrate(III) / tert-butyl alcohol; water / 96 h

5: N-ethyl-N,N-diisopropylamine / dichloromethane / Reflux

6: tetrahydrofuran / 0 °C

7: cerium(III) chloride heptahydrate; sodium tetrahydroborate / methanol / 0.25 h / 0 °C

8: Grubbs catalyst first generation / dichloromethane / 4 h / Reflux

9: tributylphosphine; diethylazodicarboxylate / toluene / 5 h / 0 °C

10: sodium methylate / methanol / 2 h / 0 °C

With Grubbs catalyst first generation; tetrachloromethane; sodium tetrahydroborate; N-Bromosuccinimide; osmium(VIII) oxide; tributylphosphine; cerium(III) chloride heptahydrate; ammonium acetate; sodium methylate; potassium carbonate; (9S,9"S)-9,9"-[phthalazine-1,4-diylbis-(oxy)]bis[10,11-dihydro-6'-methoxycinchonane]; triethylamine; N-ethyl-N,N-diisopropylamine; potassium hexacyanoferrate(III); diethylazodicarboxylate; In tetrahydrofuran; methanol; dichloromethane; water; acetone; toluene; tert-butyl alcohol; 9: |Mitsunobu Displacement;

DOI:10.1016/j.tetlet.2013.07.125

Reference yield:

C12H11BrO5 (1455230-98-4) → C17H22O8 (1455231-14-7)

Guidance literature:

Multi-step reaction with 8 steps

1: triethylamine / dichloromethane / 0.17 h

2: potassium carbonate; (9S,9"S)-9,9"-[phthalazine-1,4-diylbis-(oxy)]bis[10,11-dihydro-6'-methoxycinchonane]; osmium(VIII) oxide; potassium hexacyanoferrate(III) / tert-butyl alcohol; water / 96 h

3: N-ethyl-N,N-diisopropylamine / dichloromethane / Reflux

4: tetrahydrofuran / 0 °C

5: cerium(III) chloride heptahydrate; sodium tetrahydroborate / methanol / 0.25 h / 0 °C

6: Grubbs catalyst first generation / dichloromethane / 4 h / Reflux

7: tributylphosphine; diethylazodicarboxylate / toluene / 5 h / 0 °C

8: sodium methylate / methanol / 2 h / 0 °C

With Grubbs catalyst first generation; sodium tetrahydroborate; osmium(VIII) oxide; tributylphosphine; cerium(III) chloride heptahydrate; sodium methylate; potassium carbonate; (9S,9"S)-9,9"-[phthalazine-1,4-diylbis-(oxy)]bis[10,11-dihydro-6'-methoxycinchonane]; triethylamine; N-ethyl-N,N-diisopropylamine; potassium hexacyanoferrate(III); diethylazodicarboxylate; In tetrahydrofuran; methanol; dichloromethane; water; toluene; tert-butyl alcohol; 7: |Mitsunobu Displacement;

DOI:10.1016/j.tetlet.2013.07.125

upstream raw materials:

1,2-(methylenedioxy)-4-bromobenzene

3-(3',4'-methylenedioxybenzoyl) propanoic acid

C₁₂H₁₂O₅

C₁₂H₁₁BrO₅

Downstream raw materials:

C₂₃H₂₇NO₁₂