trans-[IrH((PPh₂(o-C₆H₄CO))2)(CO)]

Base Information

• Chemical Name: trans-[IrH((PPh₂(o-C₆H₄CO))2)(CO)]
• CAS No.: 870446-96-1
• Molecular Formula: C₃₉H₂₉IrO₃P₂
• Molecular Weight: 799.825
• Mol file: 870446-96-1.mol

Synonyms:

Chemical Property of trans-[IrH((PPh₂(o-C₆H₄CO))2)(CO)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[IrH((PPh₂(o-C₆H₄CO))2)(CO)]

There total 1 articles about trans-[IrH((PPh₂(o-C₆H₄CO))2)(CO)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[IrH((PPh2(o-C6H4CO))2H)(CO)]ClO4*0.5CH2Cl2 → trans-[IrH((PPh2(o-C6H4CO))2)(CO)] (870446-96-1,870517-91-2)

Guidance literature:

With triethylamine; In dichloromethane; under N2 atm. to soln. Ir complex in CH2Cl2 Et3N was added and stirred for 30 min at room temp.; soln. was washed with water, dried over MgSO4, and filtered, Et2O was added, ppt. was filtered, washed with Et2O and vac.-dried; elem. anal.;

DOI:10.1021/ic051219n

Reference yield:

chloroform (67-66-3,8013-54-5) + trans-[IrH((PPh2(o-C6H4CO))2)(CO)] (870446-96-1,870517-91-2) → cis-[IrH((PPh2(o-C6H4CO))2)(CO)]*1.75CHCl3

Guidance literature:

In dimethyl sulfoxide; under N2 atm. soln. Ir complex in DMSO was stirred for 48 h; water was added, ppt. was filtered, washed with Et2O, and vac.-dried, recrystn. from CHCl3-Et2O; elem. anal.;

DOI:10.1021/ic051219n