[Ti(NPh)(1,4,7-trimethyl triazacyclononane)Cl₂]

Base Information

Chemical Name:[Ti(NPh)(1,4,7-trimethyl triazacyclononane)Cl₂]
CAS No.:906666-44-2
Molecular Formula:C₁₅H₂₆Cl₂N₄Ti
Molecular Weight:381.184
Hs Code.:

[Ti(NPh)(1,4,7-trimethyl triazacyclononane)Cl<sub>2</sub>]

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Chemical Property of [Ti(NPh)(1,4,7-trimethyl triazacyclononane)Cl₂]

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Technology Process of [Ti(NPh)(1,4,7-trimethyl triazacyclononane)Cl₂]

There total 2 articles about [Ti(NPh)(1,4,7-trimethyl triazacyclononane)Cl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 402937-77-3
(HNMe₂)₂Cl₂Ti(NPh)

: 96556-05-7
N,N',N''-trimethyl-1,4,7-triazacyclononane

: 906666-44-2
[Ti(NPh)(1,4,7-trimethyl triazacyclononane)Cl₂]

Guidance literature:: In benzene; (N2 or Ar); ligand added to a soln. of Ti complex, stirred for 16 h; filtered off, washed (hexanes), dried (vac.); elem. anal.;
DOI:10.1021/om0603316

Reference yield:

: 16753-20-1
bis(dimethylamido)titanium(IV) dichloride

: 96556-05-7
N,N',N''-trimethyl-1,4,7-triazacyclononane

: 62-53-3
aniline

: 906666-44-2
[Ti(NPh)(1,4,7-trimethyl triazacyclononane)Cl₂]

Guidance literature:: In benzene; (N2 or Ar); a soln. of Ti compd. mixed with a soln. of C6H5NH2, shaken for 16 h, a soln. of (C2H4N(CH3))3 added, shaken for 2 h; solvent-removed, washed (hexanes), dried (vac.);
DOI:10.1021/om0603316

Reference yield: 53.0%

: 906666-44-2
[Ti(NPh)(1,4,7-trimethyl triazacyclononane)Cl₂]

: 917-54-4
methyllithium

: 916670-82-1
[Ti(NPh)(1,4,7-trimethyl triazacyclononane)Me₂]

Guidance literature:: In tetrahydrofuran; diethyl ether; (Ar); std. Schlenk technique; soln. of MeLi (2 equiv.) in Et2O was addedto stirred suspn. of Ti complex in THF at -78°C; mixt. was slowl y warmed to room temp.; stirred for 16 h; volatiles removed (vac.); extd. (toluene); kept at 4°C for 3 d; filtered; dried (vac.); mother liquor concd.; cooled to 4°C for 3 d; elem. anal.;
DOI:10.1021/om0606136