[Sn₂(2,6-bis[N-(2',6'-diisopropylphenyl)ketimino]phenyl^(1-))2](Sn-Sn) * n-pentane

Base Information

• Chemical Name: [Sn₂(2,6-bis[N-(2',6'-diisopropylphenyl)ketimino]phenyl^(1-))2](Sn-Sn) * n-pentane
• CAS No.: 1338251-57-2
• Molecular Formula: C₅H₁₂*C₆₈H₈₆N₄Sn₂
• Molecular Weight: 1269.03

Synonyms:

Chemical Property of [Sn₂(2,6-bis[N-(2',6'-diisopropylphenyl)ketimino]phenyl^(1-))2](Sn-Sn) * n-pentane

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Technology Process of [Sn₂(2,6-bis[N-(2',6'-diisopropylphenyl)ketimino]phenyl^(1-))2](Sn-Sn) * n-pentane

There total 2 articles about [Sn₂(2,6-bis[N-(2',6'-diisopropylphenyl)ketimino]phenyl^(1-))2](Sn-Sn) * n-pentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

[SnCl(2,6-bis[N-(2',6'-diisopropylphenyl)ketimino]phenyl(1-))] (1338257-10-5) + pentane (109-66-0,8031-35-4,9078-70-0) → [Sn2(2,6-bis[N-(2',6'-diisopropylphenyl)ketimino]phenyl(1-))2](Sn-Sn) * n-pentane (1338251-57-2)

Guidance literature:

With KC₈; In tetrahydrofuran; under Ar or N2, Schlenk technique; THF added to mixt. of Sn compd. and KC8 at -60°C, soln. stirred for 12 h; evapn. under vac., residue extd. with toluene, recrystn. from n-pentane at 0°C; elem. anal.;

DOI:10.1021/ja207538g

Reference yield:

2,6-bis[N-(2',6'-diisopropylphenyl)ketimino]phenyl-1-bromide → [Sn2(2,6-bis[N-(2',6'-diisopropylphenyl)ketimino]phenyl(1-))2](Sn-Sn) * n-pentane (1338251-57-2)

Guidance literature:

Multi-step reaction with 2 steps

1: n-butyllithium / diethyl ether; hexane

2: KC₈ / tetrahydrofuran

With n-butyllithium; KC₈; In tetrahydrofuran; diethyl ether; hexane;

DOI:10.1021/ja207538g

Reference yield: 54.3%

phosphorous (12185-10-3) + [Sn2(2,6-bis[N-(2',6'-diisopropylphenyl)ketimino]phenyl(1-))2](Sn-Sn) * n-pentane (1338251-57-2) → P4(Sn(2,6-bis[N-(2',6'-diisopropylphenyl)ketimino]phenyl(1-)))2 (1338252-16-6)

Guidance literature:

In toluene; under Ar or N2, Schlenk technique; toluene added to mixt. of Sn compd. and white phosphorus at room temp., mixt. stirred at room temp. for 2 h; evapn. under vac., residue extd. with n-pentane, soln. concd., stored at-32°C, crystals isolated; elem. anal.;

DOI:10.1021/ja207538g

upstream raw materials:

[SnCl(2,6-bis[N-(2',6'-diisopropylphenyl)ketimino]phenyl^(1-))]

pentane

Downstream raw materials:

P₄(Sn(2,6-bis[N-(2',6'-diisopropylphenyl)ketimino]phenyl^(1-)))2

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