di-μ-chloro bis(chlorothionitrosyltriphenylphosphine)-rhodium(II)

Base Information

Chemical Name:di-μ-chloro bis(chlorothionitrosyltriphenylphosphine)-rhodium(II)
CAS No.:76136-88-4
Molecular Formula:C₃₆H₃₀Cl₄N₂P₂Rh₂S₂
Molecular Weight:964.35
Hs Code.:

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Chemical Property of di-μ-chloro bis(chlorothionitrosyltriphenylphosphine)-rhodium(II)

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Technology Process of di-μ-chloro bis(chlorothionitrosyltriphenylphosphine)-rhodium(II)

There total 1 articles about di-μ-chloro bis(chlorothionitrosyltriphenylphosphine)-rhodium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 18284-36-1,27497-56-9
hydridotetakis(triphenylphosphine)rhodium(I)

: 105454-00-0,105453-99-4,5964-00-1
trithiazyl trichloride

: 76136-88-4
di-μ-chloro bis(chlorothionitrosyltriphenylphosphine)-rhodium(II)

Guidance literature:: In tetrahydrofuran; dropwise addn. of soln. of (NSCl)3 in THF to a soln. of Rh-complex withstirring at room temp. (under Ar), further stirring for 1 h; removal of solvent under vac., extn. with benzene, filtn., washing withpetroleum ether, recrystn. from benzene/petroleum ether, air drying, elem. anal.;

Reference yield: 65.0%

: 76136-88-4
di-μ-chloro bis(chlorothionitrosyltriphenylphosphine)-rhodium(II)

: Rh(NS)(P(C₆H₅)3)2Cl₂

Guidance literature:: With triphenylphosphine; In dichloromethane; addn. of PPh3 to soln. of Rh-complex in CH2Cl2 (under Ar), refluxing for 1 h; addn. of ether, centrifugation, washing with ether, recrystn. from benzene/ether, vac. drying, elem. anal.;

Reference yield: 60.0%

: 76136-88-4
di-μ-chloro bis(chlorothionitrosyltriphenylphosphine)-rhodium(II)

: 603-32-7
triphenyl-arsane

: Rh(NS)P(C₆H₅)3As(C₆H₅)3Cl₂

Guidance literature:: In dichloromethane; addn. of AsPh3 to soln. of Rh-complex in CH2Cl2 (under Ar), refluxing for 3 h; addn. of ether, centrifugation, washing with ether, recrystn. from benzene/ether, vac. drying, elem. anal.;