(μ-[5,7-di(tert-butyl)-2,3-dihydro-3,3-dimethyl-1H-phosphindole-κ2P])bis((ethane-1,2-diyl)bis[diisopropylphosphine-κP])(μ-hydrido)dirhodium*toluene

Base Information

• Chemical Name: (μ-[5,7-di(tert-butyl)-2,3-dihydro-3,3-dimethyl-1H-phosphindole-κ2P])bis((ethane-1,2-diyl)bis[diisopropylphosphine-κP])(μ-hydrido)dirhodium*toluene
• CAS No.: 401569-88-8
• Molecular Formula: C₇H₈*C₄₆H₉₃P₅Rh₂
• Molecular Weight: 1099.06
• Mol file: 401569-88-8.mol

Synonyms:

Chemical Property of (μ-[5,7-di(tert-butyl)-2,3-dihydro-3,3-dimethyl-1H-phosphindole-κ2P])bis((ethane-1,2-diyl)bis[diisopropylphosphine-κP])(μ-hydrido)dirhodium*toluene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (μ-[5,7-di(tert-butyl)-2,3-dihydro-3,3-dimethyl-1H-phosphindole-κ2P])bis((ethane-1,2-diyl)bis[diisopropylphosphine-κP])(μ-hydrido)dirhodium*toluene

There total 3 articles about (μ-[5,7-di(tert-butyl)-2,3-dihydro-3,3-dimethyl-1H-phosphindole-κ2P])bis((ethane-1,2-diyl)bis[diisopropylphosphine-κP])(μ-hydrido)dirhodium*toluene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

[5,7-di(tert-butyl)-2,3-dihydro-3,3-dimethyl-1H-phosphindole-κP]((ethane-1,2-diyl)bis[diisopropylphosphine-κP])hydrorhodium (401569-85-5) + toluene (108-88-3,15644-74-3,16713-13-6) → (μ-[5,7-di(tert-butyl)-2,3-dihydro-3,3-dimethyl-1H-phosphindole-κ2P])bis((ethane-1,2-diyl)bis[diisopropylphosphine-κP])(μ-hydrido)dirhodium*toluene (401569-88-8)

Guidance literature:

In toluene; under N2atm. Rh complex in toluene was heated at 80°C for 72 h; mixt. was cooled to room temp., concd., filtered and stored at -30°C for 48 h; elem. anal.;

DOI:10.1002/1522-2675(20011017)84:10<2958::AID-HLCA2958>3.0.CO;2-L

Reference yield:

(2,4,6-tri-tert-butylphenyl)phosphine (83115-12-2) → (μ-[5,7-di(tert-butyl)-2,3-dihydro-3,3-dimethyl-1H-phosphindole-κ2P])bis((ethane-1,2-diyl)bis[diisopropylphosphine-κP])(μ-hydrido)dirhodium*toluene (401569-88-8)

Guidance literature:

Multi-step reaction with 2 steps

1: pentane

2: toluene

In toluene; pentane;

DOI:10.1002/1522-2675(20011017)84:10<2958::AID-HLCA2958>3.0.CO;2-L

Reference yield:

[Rh(η3-benzyl)(bis(diisopropylphosphino)ethane)] → (μ-[5,7-di(tert-butyl)-2,3-dihydro-3,3-dimethyl-1H-phosphindole-κ2P])bis((ethane-1,2-diyl)bis[diisopropylphosphine-κP])(μ-hydrido)dirhodium*toluene (401569-88-8)

Guidance literature:

Multi-step reaction with 2 steps

1: pentane

2: toluene

In toluene; pentane;

DOI:10.1002/1522-2675(20011017)84:10<2958::AID-HLCA2958>3.0.CO;2-L

upstream raw materials:

[5,7-di(tert-butyl)-2,3-dihydro-3,3-dimethyl-1H-phosphindole-κP]((ethane-1,2-diyl)bis[diisopropylphosphine-κP])hydrorhodium

toluene

(2,4,6-tri-tert-butylphenyl)phosphine