3-azido-5-(azidomethyl)phenol

Base Information

Chemical Name:3-azido-5-(azidomethyl)phenol
CAS No.:1620809-46-2
Molecular Formula:C₇H₆N₆O
Molecular Weight:190.164
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-azido-5-(azidomethyl)phenol

Chemical Property:

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Technology Process of 3-azido-5-(azidomethyl)phenol

There total 6 articles about 3-azido-5-(azidomethyl)phenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1157852-36-2
2-[3-azido-5-(azidomethyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1620809-46-2
3-azido-5-(azidomethyl)phenol

Guidance literature:: With dihydrogen peroxide; In water; at 20 ℃; for 16h;
DOI:10.1002/ejoc.201402516

Reference yield:

: 1620809-38-2
(3-ethoxycarbonyl-5-iodo)phenylboronic acid pinacol ester

: 1620809-46-2
3-azido-5-(azidomethyl)phenol

Guidance literature:: Multi-step reaction with 5 steps

1: trimethylsilylazide; copper(l) chloride; potassium fluoride / methanol / 7 h / 20 - 70 °C

2: diisobutylaluminium hydride / hexane; tetrahydrofuran / 3 h / -78 °C / Inert atmosphere

3: diphenyl phosphoryl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene / toluene / 25 h / 20 °C / Inert atmosphere

4: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / dimethyl sulfoxide / 3 h / 20 - 80 °C / Inert atmosphere

5: dihydrogen peroxide / water / 16 h / 20 °C

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium fluoride; trimethylsilylazide; diphenyl phosphoryl azide; dihydrogen peroxide; potassium acetate; diisobutylaluminium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; copper(l) chloride; In tetrahydrofuran; methanol; hexane; water; dimethyl sulfoxide; toluene; 4: |Miyaura Borylation Reaction;
DOI:10.1002/ejoc.201402516

Reference yield:

: 58313-23-8
3-iodobenzoic acid methyl ester

: 1620809-46-2
3-azido-5-(azidomethyl)phenol

Guidance literature:: Multi-step reaction with 6 steps

1: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine / hexane / 39 h / 20 °C / Inert atmosphere

2: trimethylsilylazide; copper(l) chloride; potassium fluoride / methanol / 7 h / 20 - 70 °C

3: diisobutylaluminium hydride / hexane; tetrahydrofuran / 3 h / -78 °C / Inert atmosphere

4: diphenyl phosphoryl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene / toluene / 25 h / 20 °C / Inert atmosphere

5: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / dimethyl sulfoxide / 3 h / 20 - 80 °C / Inert atmosphere

6: dihydrogen peroxide / water / 16 h / 20 °C

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium fluoride; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; trimethylsilylazide; diphenyl phosphoryl azide; dihydrogen peroxide; potassium acetate; diisobutylaluminium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; 4,4'-di-tert-butyl-2,2'-bipyridine; copper(l) chloride; In tetrahydrofuran; methanol; hexane; water; dimethyl sulfoxide; toluene; 5: |Miyaura Borylation Reaction;
DOI:10.1002/ejoc.201402516